1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one

Base Information

Chemical Name:1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one
CAS No.:59870-82-5
Molecular Formula:C14H19O4P
Molecular Weight:282.27200
Hs Code.:
DSSTox Substance ID:DTXSID001346756
Nikkaji Number:J354.911I,J502.605I
Mol file:59870-82-5.mol

Synonyms:1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one;59870-82-5;DTXSID001346756;(E)-1-diethoxyphosphoryl-4-phenylbut-3-en-2-one;diethyl (3E)-2-oxo-4-phenyl-3-butenylphosphonate;1-DIETHOXYPHOSPHORYL-4-PHENYL-3-BUTEN-2-ONE;Q63409672;(E)-2-Oxo-4-phenyl-3-butenylphosphonic acid diethyl ester

Suppliers and Price of 1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one

Chemical Property:

Boiling Point:190 - 195 °C (1 mmHg)
PSA：62.41000
LogP:3.53500
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:282.10209608
Heavy Atom Count:19
Complexity:335

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOP(=O)(CC(=O)C=CC1=CC=CC=C1)OCC
Isomeric SMILES:CCOP(=O)(CC(=O)/C=C/C1=CC=CC=C1)OCC

Technology Process of 1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one

There total 2 articles about 1-Diethoxyphosphinyl-4-phenyl-3-buten-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 10419-77-9
diethyl iodomethanephosphonate

: 103-26-4,1754-62-7
methyl cinnamate

: 59870-82-5
oxo-2 phenyl-4 butenyl-3,4 phosphonate de diethyle

Guidance literature:: With magnesium; In tetrahydrofuran; at 20 ℃;
DOI:10.1055/s-2002-33653

Reference yield:

: 683-08-9
Diethyl methylphosphonate

: 102-92-1,17082-09-6
cinnamoyl chloride

: 59870-82-5
oxo-2 phenyl-4 butenyl-3,4 phosphonate de diethyle

Guidance literature:: Multistep reaction; (i) nBuLi, hexane, THF, (ii) Cu₂I₂, (iii) /BRN= 386079/, Et₂O;
DOI:10.1016/0040-4020(78)88099-5

Reference yield: 58.0%

: 59870-82-5
oxo-2 phenyl-4 butenyl-3,4 phosphonate de diethyle

: 82102-09-8
amino-2 phenyl-4 butylphosphonate de diethyle

Guidance literature:: With ammonium acetate; hydrogenchloride; sodium cyanoborohydride; In methanol; for 120h; Ambient temperature;
DOI:10.1016/S0040-4020(01)98903-3