6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)-

Base Information

Chemical Name:6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)-
CAS No.:606128-67-0
Molecular Formula:C15H20O5S
Molecular Weight:312.387
Hs Code.:

Synonyms:

Suppliers and Price of 6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)-

There total 6 articles about 6-Cycloheptene-1,2,4-triol, 3,5-dimethyl-7-(phenylsulfonyl)-, (1S,2S,3R,4R,5S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 606128-51-2
(1S, 2S, 7S)-4-Benzenesulfonyl-2,7-dimethylcyclohepta-3,5-dienol

: 606128-67-0
(1S, 2S, 3R, 4R, 5S)-7-Benzenesulfonyl-3,5-dimethylcyclohept-6-ene-1,2,4-triol

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; at 20 ℃; for 36h;

Reference yield:

: 882-33-7
diphenyldisulfane

: 606128-67-0
(1S, 2S, 3R, 4R, 5S)-7-Benzenesulfonyl-3,5-dimethylcyclohept-6-ene-1,2,4-triol

Guidance literature:: Multi-step reaction with 5 steps

1.1: tetrahydrofuran / -78 °C

1.2: tetrahydrofuran / -78 - 20 °C

2.1: trimethylsilyl triflate; (C₂H₅)3N / CH₂Cl₂ / Heating

3.1: n-C₄H₉Li / tetrahydrofuran / 1.5 h / -78 - -5 °C

3.2: tetrahydrofuran / -90 - -50 °C

4.1: m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / 25 °C

5.1: m-chloroperbenzoic acid; OsO₄

With osmium(VIII) oxide; n-butyllithium; trimethylsilyl trifluoromethanesulfonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200350955

Reference yield:

: 606128-45-4
(1R, 2S)-2-Methyl-5-phenylsulfanylcyclohepta-3,5-dienol

: 606128-67-0
(1S, 2S, 3R, 4R, 5S)-7-Benzenesulfonyl-3,5-dimethylcyclohept-6-ene-1,2,4-triol

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-C₄H₉Li / tetrahydrofuran / 1.5 h / -78 - -5 °C

1.2: tetrahydrofuran / -90 - -50 °C

2.1: m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / 25 °C

3.1: m-chloroperbenzoic acid; OsO₄

With osmium(VIII) oxide; n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200350955