1,2-Decanediol, diacetate

Base Information

• Chemical Name: 1,2-Decanediol, diacetate
• CAS No.: 60671-14-9
• Molecular Formula: C14H26O4
• Molecular Weight: 258.358
• Mol file: 60671-14-9.mol

Synonyms:decane-1,2-diyl diacetate;1,2-Decanediol,diacetate;1,2-Diacetoxy-decan;acetic acid 2-acetoxy-decyl ester;2-Acetoxydecylacetat;1,2-diacetoxydecane;

Chemical Property of 1,2-Decanediol, diacetate

Chemical Property:

• Boiling Point: 320.3±15.0 °C(Predicted)
• PSA: 115.06000
• Density: 0.967±0.06 g/cm3(Predicted)
• LogP: 2.27200

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Decanediol, diacetate

There total 4 articles about 1,2-Decanediol, diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) + acetic acid (64-19-7,77671-22-8) → decane-2-yl acetate (1534-32-3) + n-decyl acetate (112-17-4) + acetic acid 2-acetoxy-decyl ester (60671-14-9)

Guidance literature:

With ammonium persulfate; cobalt(II) acetate; In dodecane; for 6h; Product distribution; Heating; other catalysts and amount of oxidant;

DOI:10.1016/S0040-4020(01)91793-4

Reference yield:

acetic anhydride (108-24-7) + 4-octyl-1,3-dioxolan-2-one (99260-48-7) → decane-2-yl acetate (1534-32-3) + n-decyl acetate (112-17-4) + acetic acid 2-acetoxy-decyl ester (60671-14-9)

Guidance literature:

With pyridine; 18-crown-6 ether; tert-butylamine; Yield given. Multistep reaction. Yields of byproduct given; 1.) ether, room temperature;

Reference yield:

acetic anhydride (108-24-7) + D,L-4-octyl-1,3-dioxolan-2-thione (86170-74-3) → decane-2-yl acetate (1534-32-3) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + n-decyl acetate (112-17-4) + acetic acid 2-acetoxy-decyl ester (60671-14-9)

Guidance literature:

With pyridine; 18-crown-6 ether; tert-butylamine; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, room temperature;

upstream raw materials:

acetic anhydride

D,L-4-octyl-1,3-dioxolan-2-thione

4-octyl-1,3-dioxolan-2-one

1-Decene

Downstream raw materials:

(S)-decane-1,2-diol

(R)-decane-1,2-diol