1534-32-3Relevant academic research and scientific papers
Stabilization of long-chain intermediates in solution. octyl radicals and cations
Teodorovi?, Aleksandar V.,Badjuk, Dalibor M.,Stevanovi?, Nenad,Pavlovi?, Radoslav Z.
, p. 19 - 24 (2013/06/26)
The rearrangements of 1-octyl, 1-decyl and 1-tridecyl intermediates obtained from thermal lead(IV) acetate (LTA) decarboxylation of nonanoic, undecanoic and tetradecanoic acid were investigated experimentally through analysis and distribution of the products. The relationships between 1,5-, 1,6- and possibly existing 1,7-homolytic hydrogen transfer in 1-octyl-radical, as well as successive 1,2-hydride shift in corresponding cation have been computed via Monte-Carlo method. Taking into account that ratios of 1,5-/1,6-homolytic rearrangements in 1-octyl- and 1-tridecyl radical are approximately the same, the simulation shows very low involvement of 1,7-hydrogen rearrangement (1,5-/1,6-/1,7-hydrogen rearrangement = 85:31:1) in 1-octyl radical.
ALKENE OXIDATION BY AN IRON(II)/PERSULFATE/ACETIC ACID SYSTEM
Fristad, William E.,Peterson, John R.
, p. 1469 - 1476 (2007/10/02)
Mono- and disubstituted alkenes were converted to trans-vicinal diacetates by heating with an iron(II)/persulfate/acetic acid system.The synthetic utility and limitations were identified.A mechanism for the transformation is proposed wich involves an initial addition of sulfate radical anion to the alkene followed by solvolysis, addition, hydrolysis, and acetylation.
IRON(II) CATALYZED ODIDATION OF ALKENES TO VICINAL DIACETATES
Fristad, William E.,Peterson, John R.
, p. 4547 - 4550 (2007/10/02)
Mono- and disubstituted alkenes are converted to trans-vicinal diacetates by heating with an acetic acid solution of ammonium persulfate and a ferrous sulfate catalyst.
OXIDATION OF N-ALKYL-N'-TOSYLHYDRAZINES WITH Hg(OAc)2. A NEW SYNTHESIS OF ETHERS
Gasparrini, F.,Caglioti, L.,Misiti, D.,Palmieri, G.,Ballini,R.
, p. 3609 - 3613 (2007/10/02)
N-Alkyl-N'-tosylhydrazines with Hg(OAc)2 in the presence of alcohols or phenol give high yields of corresponding ethers.Reactions in the presence of acetic acid are also examined.
The Deoxygenation of NN-Dialkylaminothiocarbonyloxyalkanes
Barrett, Anthony G. M.,Prokopiou, Panayiotis A.,Barton, Derek H. R.
, p. 1510 - 1516 (2007/10/02)
The title compounds were converted into alkanes in high yield on reduction with potassium and 18-crown-6 in t-butylamine.Thereby both primary and secondary alcohols were conveniently deoxygenated.
