Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-

Base Information

Chemical Name:Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-
CAS No.:61062-50-8
Molecular Formula:C10H18
Molecular Weight:138.253
Hs Code.:
DSSTox Substance ID:DTXSID70453726
Nikkaji Number:J510.794F
Wikidata:Q82274937

Synonyms:Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-;61062-50-8;DTXSID70453726;(4R)-4-tert-Butyl-1-cyclohexene

Suppliers and Price of Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:138.140850574
Heavy Atom Count:10
Complexity:126

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)C1CCC=CC1
Isomeric SMILES:CC(C)(C)[C@@H]1CCC=CC1

Technology Process of Cyclohexene, 4-(1,1-dimethylethyl)-, (R)-

There total 6 articles about Cyclohexene, 4-(1,1-dimethylethyl)-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 5009-36-9
cis-1-bromo-4-tert-butylcyclohexane

: 61062-50-8
(R)-4-(tert-butyl)cyclohexene

Guidance literature:: With lithium diisopropylamide; In tetrahydrofuran; for 1.5h;
DOI:10.1021/acs.joc.9b01428

Reference yield:

: 249743-98-4
(R)-cis-2-bromophenyl 4-(tert-butyl)cyclohexyl sulfoxide

: 61062-50-8
(R)-4-(tert-butyl)cyclohexene

: 77242-40-1
(4S)-(-)-4-tert-butylcyclohexene

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 10 ℃; Title compound not separated from byproducts.; Irradiation;
DOI:10.1021/ol990859p

Reference yield:

: 98-52-2
4-(1,1-dimethylethyl)-cyclohexanol

: 61062-50-8
(R)-4-(tert-butyl)cyclohexene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 29 percent / iodine; imidazole; PPh₃ / toluene / 4 h / 60 °C

2.1: Mg / diethyl ether

2.2: diethyl ether; benzene / 0 - 20 °C

3.1: lithium diisopropylamide / tetrahydrofuran / -30 °C

3.2: water / tetrahydrofuran

4.1: Bu₃SnH; AIBN / benzene / 10 °C / Irradiation

With 1H-imidazole; 2,2'-azobis(isobutyronitrile); iodine; tri-n-butyl-tin hydride; magnesium; triphenylphosphine; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; toluene; benzene;
DOI:10.1021/ol990859p