[(8aR)-8a-methyl-3-(propan-2-yl)-1,2,4,5,8,8a-hexahydroazulen-6-yl]methyl 4-methoxybenzoate

Base Information

• Chemical Name: [(8aR)-8a-methyl-3-(propan-2-yl)-1,2,4,5,8,8a-hexahydroazulen-6-yl]methyl 4-methoxybenzoate
• CAS No.: 104697-03-2
• Molecular Formula: C₂₃H₃₀O₃
• Molecular Weight: 354.489
• Mol file: 104697-03-2.mol

Synonyms:

Chemical Property of [(8aR)-8a-methyl-3-(propan-2-yl)-1,2,4,5,8,8a-hexahydroazulen-6-yl]methyl 4-methoxybenzoate

Chemical Property:

• Vapor Pressure: 4.27E-09mmHg at 25°C
• Boiling Point: 472.5°Cat760mmHg
• Flash Point: 203.4°C
• Density: 1.08g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(8aR)-8a-methyl-3-(propan-2-yl)-1,2,4,5,8,8a-hexahydroazulen-6-yl]methyl 4-methoxybenzoate

There total 1 articles about [(8aR)-8a-methyl-3-(propan-2-yl)-1,2,4,5,8,8a-hexahydroazulen-6-yl]methyl 4-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C15H24O + 4-methoxy-benzoyl chloride (100-07-2) → 14-p-methoxybenzoyl-dauca-4,8-diene (104697-03-2) + (+)-14-p-anisoyloxydauc-4,8-diene

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 ℃; for 18h; Overall yield = 61 %; Overall yield = 5.5 mg; enantioselective reaction; Inert atmosphere;

DOI:10.1002/chem.201302353

upstream raw materials:

4-methoxy-benzoyl chloride

Refernces