1-(Dibromomethyl)-2-methylcyclohexan-1-ol

Base Information

• Chemical Name: 1-(Dibromomethyl)-2-methylcyclohexan-1-ol
• CAS No.: 61415-09-6
• Molecular Formula: C₈H₁₄Br₂O
• Molecular Weight: 286.007
• DSSTox Substance ID: DTXSID40508454
• Mol file: 61415-09-6.mol

Synonyms:1-(Dibromomethyl)-2-methylcyclohexan-1-ol;61415-09-6;DTXSID40508454

Chemical Property of 1-(Dibromomethyl)-2-methylcyclohexan-1-ol

Chemical Property:

• XLogP3: 3.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 285.93909
• Heavy Atom Count: 11
• Complexity: 138

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CCCCC1(C(Br)Br)O

Technology Process of 1-(Dibromomethyl)-2-methylcyclohexan-1-ol

There total 2 articles about 1-(Dibromomethyl)-2-methylcyclohexan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methylcyclohexanone (583-60-8) + 1,1-dibromomethane (74-95-3) → 1-Dibrommethyl-2-methylcyclohexanol (61415-09-6)

Guidance literature:

With lithium dicyclohexylamide; In tetrahydrofuran; at -78 ℃; Product distribution; var. carbonyl comp.;

DOI:10.1016/S0040-4039(01)82009-8

Reference yield:

→ 1-Dibrommethyl-2-methylcyclohexanol (61415-09-6)

Guidance literature:

2-Methylcyclohexanon, Dibrommethyllithium;

Reference yield:

1-Dibrommethyl-2-methylcyclohexanol (61415-09-6) → 1-[1-Bromo-meth-(Z)-ylidene]-2-methyl-cyclohexane (81060-48-2) + 1-[1-Bromo-meth-(E)-ylidene]-2-methyl-cyclohexane (81060-41-5)

Guidance literature:

With acetic acid; zinc; In dichloromethane; for 18h; Yield given. Yields of byproduct given; Heating;

DOI:10.1016/S0040-4039(01)82009-8

upstream raw materials:

2-Methylcyclohexanone

1,1-dibromomethane

Downstream raw materials:

1-[1-Bromo-meth-(Z)-ylidene]-2-methyl-cyclohexane

1-[1-Bromo-meth-(E)-ylidene]-2-methyl-cyclohexane