3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-

Base Information

Chemical Name:3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-
CAS No.:61539-00-2
Molecular Formula:C13H16O2S2
Molecular Weight:268.401
Hs Code.:
DSSTox Substance ID:DTXSID40484906

Synonyms:61539-00-2;3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-;DTXSID40484906

Suppliers and Price of 3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:268.05917210
Heavy Atom Count:17
Complexity:286

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)C(=C(SC)SC)C1=CC=C(C=C1)OC

Technology Process of 3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)-

There total 2 articles about 3-Buten-2-one, 3-(4-methoxyphenyl)-4,4-bis(methylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 17649-86-4
4,4-bis(methylthio)but-3-en-2-one

: 61539-00-2
3-(4-methoxyphenyl)-4,4-bis(methylsulfanyl)-3-buten-2-one

Guidance literature:: With tris(bipyridine)ruthenium(II) dichloride hexahydrate; In dimethyl sulfoxide; at 25 ℃; for 15h; Irradiation; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.orglett.7b03223

Reference yield:

: 75-15-0,12122-00-8
carbon disulfide

: 122-84-9
4-methoxybenzyl methyl ketone

: 74-88-4
methyl iodide

: 61539-00-2
3-(4-methoxyphenyl)-4,4-bis(methylsulfanyl)-3-buten-2-one

Guidance literature:: Multistep reaction; (i) NaOtBu, (ii) /BRN= 969135/;
DOI:10.1016/0040-4020(76)85174-5

Reference yield: 71.0%

: 61539-00-2
3-(4-methoxyphenyl)-4,4-bis(methylsulfanyl)-3-buten-2-one

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: S¹-methyl 3-chloro-4-(4-methoxyphenyl)-5-(methylsulfanyl)-2,4-pentadienethioate

Guidance literature:: N,N-dimethyl-formamide; With trichlorophosphate;

3-(4-methoxyphenyl)-4,4-bis(methylsulfanyl)-3-buten-2-one; at 20 ℃; for 72h;

With potassium carbonate; In water; Further stages.;
DOI:10.1016/j.tet.2004.04.017