ACENAPHTHENEQUINONE DIOXIME

Base Information

• Chemical Name: ACENAPHTHENEQUINONE DIOXIME
• CAS No.: 1932-08-7
• Molecular Formula: C12H8 N2 O2
• Molecular Weight: 212.208
• Mol file: 1932-08-7.mol

Synonyms:1,2-Acenaphthylenedione,dioxime (9CI); Acenaphthenequinone, dioxime (7CI,8CI); 1,2-Acenaphthenequinonedioxime; NSC 31680

Chemical Property of ACENAPHTHENEQUINONE DIOXIME

Chemical Property:

• Vapor Pressure: 9.69E-09mmHg at 25°C
• Boiling Point: 446.1°Cat760mmHg
• Flash Point: 223.6°C
• PSA: 65.18000
• Density: 1.47g/cm³
• LogP: 2.21000

Purity/Quality:

98%,99%, ^*data from raw suppliers

Acenaphthenequinone Dioxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ACENAPHTHENEQUINONE DIOXIME

There total 3 articles about ACENAPHTHENEQUINONE DIOXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

acenaphthene quinone (82-86-0) → N,N’-dihydroxy-1,2-acenaphthylenediimine (1932-08-7)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In ethanol; at 20 ℃; for 24h;

DOI:10.1177/1747519819831829

Reference yield:

acenaphthene (83-32-9) → N,N’-dihydroxy-1,2-acenaphthylenediimine (1932-08-7)

Guidance literature:

Multi-step reaction with 2 steps

1: glacial acetic acid; Na₂Cr₂O₇ / 100 °C

2: alcohol; hydroxylamine hydrochloride

With sodium dichromate; ethanol; hydroxylamine hydrochloride; acetic acid;

Reference yield:

→ N,N’-dihydroxy-1,2-acenaphthylenediimine (1932-08-7)

Guidance literature:

gemaess Ann., 276, 10 (1893);

upstream raw materials:

acenaphthene quinone

acenaphthene

Downstream raw materials:

acenaphtho[1,2-c]-1,2,5-oxadiazole 7-oxide

8-(5-phenyl-isoxazol-3-yl)-naphthalene-1-carbonitrile

acenaphthene quinone

Acenaphtho<1,2-c>furazan

Refernces

• 1、 Plater, M. John,Harrison, William T. A.,Killah, Ross. "Potential photoacid generators based on oxime sulfonates". . p. 26 - 33. Retrieved 2019/06/03.