Acenaphth[1,2-c][1,2,5]oxadiazole 7-oxide

Base Information

• Chemical Name: Acenaphth[1,2-c][1,2,5]oxadiazole 7-oxide
• CAS No.: 7760-55-6
• Molecular Formula: C₁₂H₆N₂O₂
• Molecular Weight: 210.192
• Mol file: 7760-55-6.mol

Synonyms:acenaphthofuroxan;8-Oxa-7,9-diaza-cyclopenta[a]acenaphthylene 7-oxide;acenaphth[1,2-c][1,2,5]oxadiazole-7-oxide;Acenaphto<1,2>furoxan;Acenaphth[1,2-c][1,2,5]oxadiazol-7-oxid;acenaphtho[1,2-c][1,2,5]oxadiazole 7-oxide;Acenaphtho<1,2-c>furazan-1-oxid;

Chemical Property of Acenaphth[1,2-c][1,2,5]oxadiazole 7-oxide

Chemical Property:

• PSA: 51.49000
• LogP: 2.90370

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acenaphth[1,2-c][1,2,5]oxadiazole 7-oxide

There total 3 articles about Acenaphth[1,2-c][1,2,5]oxadiazole 7-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

N,N’-dihydroxy-1,2-acenaphthylenediimine (1932-08-7) → acenaphtho[1,2-c]-1,2,5-oxadiazole 7-oxide (7760-55-6)

Guidance literature:

With [bis(acetoxy)iodo]benzene; In dichloromethane; at 25 ℃; for 0.75h; Schlenk technique;

DOI:10.1039/d1nj05510k

Reference yield:

acenaphthene quinone (82-86-0) → acenaphtho[1,2-c]-1,2,5-oxadiazole 7-oxide (7760-55-6)

Guidance literature:

Multi-step reaction with 2 steps

1: hydroxylamine hydrochloride

2: alkaline sodium hypochlorite solution

With alkaline sodium hypochlorite solution; hydroxylamine hydrochloride;

Reference yield:

→ acenaphtho[1,2-c]-1,2,5-oxadiazole 7-oxide (7760-55-6)

Guidance literature:

Dioxim X, Bleitetraacetat in Eisessig (bei 60-70grad);

upstream raw materials:

N,N’-dihydroxy-1,2-acenaphthylenediimine

acenaphthene quinone

Downstream raw materials:

Acenaphtho<1,2-c>furazan

8-(5-phenyl-isoxazol-3-yl)-naphthalene-1-carbonitrile