4H-Fluoren-4-one, 1,2,3,9-tetrahydro-

Base Information

Chemical Name:4H-Fluoren-4-one, 1,2,3,9-tetrahydro-
CAS No.:61601-33-0
Molecular Formula:C13H12O
Molecular Weight:184.238
Hs Code.:
DSSTox Substance ID:DTXSID70485385
Nikkaji Number:J2.422.430I
Wikidata:Q82324526

Synonyms:4H-Fluoren-4-one, 1,2,3,9-tetrahydro-;1,2,3,9-tetrahydro-fluoren-4-one;61601-33-0;DTXSID70485385;1,2,3,9-tetrahydro-4H-fluoren-4-one

Suppliers and Price of 4H-Fluoren-4-one, 1,2,3,9-tetrahydro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4H-Fluoren-4-one, 1,2,3,9-tetrahydro-

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:184.088815002
Heavy Atom Count:14
Complexity:300

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2=C(C(=O)C1)C3=CC=CC=C3C2

Technology Process of 4H-Fluoren-4-one, 1,2,3,9-tetrahydro-

There total 1 articles about 4H-Fluoren-4-one, 1,2,3,9-tetrahydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 119826-71-0
3-(2-bromobenzyl)cyclohex-2-en-1-one

: 61601-33-0
3,4-dihydro-2H-fluoren-1(9H)-one

: 103130-93-4
3-benzylcyclohex-2-en-1-one

Guidance literature:: With sodium hydrogencarbonate; Pd(OAc)2(Ph₃)2; In N,N-dimethyl-formamide; at 80 ℃; for 36h;
DOI:10.1016/S0040-4039(00)80376-7

Reference yield: 65.0%

: 14633-54-6
cyclopropylphenylsulfide

: 61601-33-0
3,4-dihydro-2H-fluoren-1(9H)-one

: 904328-77-4
2,3,4,9-tetrahydro-4-[1-(phenylthio)cyclopropyl]-1H-fluoren-4-ol

Guidance literature:: cyclopropylphenylsulfide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 1.5h;

With cerium(III) chloride; In tetrahydrofuran; hexane; at -78 ℃;

3,4-dihydro-2H-fluoren-1(9H)-one; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1016/j.jorganchem.2006.03.023

Reference yield:

: 61601-33-0
3,4-dihydro-2H-fluoren-1(9H)-one

: 2,3-dihydro-4-[1-(phenylthio)cyclopropyl]-1H-fluorene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / hexane; tetrahydrofuran / 1.5 h / 0 °C

1.2: CeCl₃ / hexane; tetrahydrofuran / -78 °C

1.3: 65 percent / hexane; tetrahydrofuran / -78 - 20 °C

2.1: 78 percent / aq. HBF₄ / benzene / 14 h / 70 °C

With tetrafluoroboric acid; n-butyllithium; In tetrahydrofuran; hexane; benzene;
DOI:10.1016/j.jorganchem.2006.03.023