Benzenepropaneperoxoic acid, a-phenyl-, 1,1-dimethylethyl ester

Base Information

• Chemical Name: Benzenepropaneperoxoic acid, a-phenyl-, 1,1-dimethylethyl ester
• CAS No.: 61609-14-1
• Molecular Formula: C19H22O3
• Molecular Weight: 298.382
• Mol file: 61609-14-1.mol

Synonyms:

Chemical Property of Benzenepropaneperoxoic acid, a-phenyl-, 1,1-dimethylethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Benzenepropaneperoxoic acid, a-phenyl-, 1,1-dimethylethyl ester

There total 1 articles about Benzenepropaneperoxoic acid, a-phenyl-, 1,1-dimethylethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

tert.-butylhydroperoxide (75-91-2) + 2,3-diphenylpropanoic acid (94942-89-9) → 2,3-Diphenylperoxypropionsaeure-tert.butylester (61609-14-1)

Guidance literature:

tert.-butylhydroperoxide; 2,3-diphenylpropanoic acid; With dmap; In dichloromethane; water; at 0 ℃; for 0.166667h; Inert atmosphere;

With dicyclohexyl-carbodiimide; In dichloromethane; water; at 0 ℃; for 1.5h; Inert atmosphere;

DOI:10.1021/acs.orglett.1c03355

Reference yield:

2,3-Diphenylperoxypropionsaeure-tert.butylester (61609-14-1) → C14H13N3 + C14H13N3

Guidance literature:

With iron(II) triflate; trimethylsilylazide; C₅₈H₆₂N₂O₃; In tetrahydrofuran; at 20 ℃; for 12h; Overall yield = 77 percent; Overall yield = 34 mg; enantioselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.1c03355

upstream raw materials:

tert.-butylhydroperoxide

2,3-diphenylpropanoic acid