Ethyl ethenyl(methyl)phosphinate

Base Information

• Chemical Name: Ethyl ethenyl(methyl)phosphinate
• CAS No.: 61753-00-2
• Molecular Formula: C5H11O2P
• Molecular Weight: 106.06000
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID20544037
• Nikkaji Number: J847.556C
• Mol file: 61753-00-2.mol

Synonyms:Ethyl ethenyl(methyl)phosphinate;61753-00-2;1-[ethenyl(methyl)phosphoryl]oxyethane;SCHEMBL779857;DTXSID20544037

Chemical Property of Ethyl ethenyl(methyl)phosphinate

Chemical Property:

• PSA: 49.77000
• LogP: 1.25100
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 134.04966659
• Heavy Atom Count: 8
• Complexity: 120

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOP(=O)(C)C=C

Technology Process of Ethyl ethenyl(methyl)phosphinate

There total 2 articles about Ethyl ethenyl(methyl)phosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

Vinyl bromide (593-60-2,25951-54-6) + ethyl methylphosphinate (16391-07-4) → Ethyl ethenylmethylphosphinate (61753-00-2)

Guidance literature:

With triethylamine; bis-triphenylphosphine-palladium(II) chloride; at 100 ℃; for 1h;

Reference yield:

ethyl(2-bromoethyl)(methyl)phosphinate (52399-90-3) → Ethyl ethenylmethylphosphinate (61753-00-2)

Guidance literature:

With orthoformic acid triethyl ester; for 2h; Heating;

Reference yield:

diethyl 2-phenylaminomalonate (6414-58-0) + Ethyl ethenylmethylphosphinate (61753-00-2) → 4-(Hydroxy-methyl-phosphinoyl)-2-phenylamino-butyric acid

Guidance literature:

With hydrogenchloride; Multistep reaction;

upstream raw materials:

Vinyl bromide

ethyl methylphosphinate

ethyl(2-bromoethyl)(methyl)phosphinate

Downstream raw materials:

2-(N-methyl-N-benzylamino)-4-(methyl-hydroxyphosphinyl)-butanoic acid