Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-

Base Information

Chemical Name:Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-
CAS No.:20259-40-9
Molecular Formula:C₁₄H₂₉Al
Molecular Weight:224.366
Hs Code.:
Mol file:20259-40-9.mol

Synonyms:20259-40-9;Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-;Dibutyl-trans-hexenylaluminum;Diisobutyl[(E)-1-hexenyl]aluminum

Suppliers and Price of Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-

Chemical Property:

Vapor Pressure:188mmHg at 25°C
Boiling Point:62.8°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:5.53010
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:8
Exact Mass:224.2084643
Heavy Atom Count:15
Complexity:149

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCC=C[Al](CC(C)C)CC(C)C
Isomeric SMILES:CCCC/C=C/[Al](CC(C)C)CC(C)C

Technology Process of Aluminum, (1E)-1-hexenylbis(2-methylpropyl)-

There total 1 articles about Aluminum, (1E)-1-hexenylbis(2-methylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14343-59-0
1,1-bis(diisobutylaluminium)hexane

: 7517-02-4
isopropoxydiisobutylaluminum

: (((CH₃)2CHCH₂)2Al)CH((CH₂)4CH₃)Al(CH₂CH(CH₃)2)OCH(CH₃)2

: 20259-40-9,26076-75-5
diisobutyl(hex-1-en-1-yl)alane

Guidance literature:: With acetone; In pentane; byproducts: isobutene; Me2CO was dropwise added to soln. of alane (1:1 molar ratio) in pentane at -75°C under N2 atmosphere, mixt. was allowed to warm to room temp., refluxed for 30 min; isobutene evolved was collected in a gas burette and analysed by GLC, solvent from the reaction mixt. was distilled off; hydrolysis of residue observed yielding i-PrOH, i-butanol, i-butane, hexane, and 1-hexene (extrn. with ether and analys by GLC);
DOI:10.1016/0022-328X(87)80320-0

Reference yield: 94.0%

: 709-63-7
1-(4-trifluoromethylphenyl)ethanone

: 20259-40-9,26076-75-5
diisobutyl(hex-1-en-1-yl)alane

: 2-((4-trifluoromethyl)phenyl)oct-3-en-2-ol

Guidance literature:: With titanium(IV) isopropylate; (S)-[1,1']-binaphthalenyl-2,2'-diol; In tetrahydrofuran; at 0 - 20 ℃; for 24h; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol801999u

Reference yield: 92.0%

: 20259-40-9,26076-75-5
diisobutyl(hex-1-en-1-yl)alane

: 100-19-6
(4-nitrophenyl)ethanone

: 2-(4-nitrophenyl)oct-3-en-2-ol

Guidance literature:: With titanium(IV) isopropylate; (S)-[1,1']-binaphthalenyl-2,2'-diol; In tetrahydrofuran; at 0 - 20 ℃; for 24h; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol801999u