1-(2-chlorophenyl)-N-[2-[(2-chlorophenyl)methylideneamino]ethyl]methanimine

Base Information

• Chemical Name: 1-(2-chlorophenyl)-N-[2-[(2-chlorophenyl)methylideneamino]ethyl]methanimine
• CAS No.: 81512-53-0
• Molecular Formula: C16H14Cl2N2
• Molecular Weight: 305.207
• Mol file: 81512-53-0.mol

Synonyms:

Chemical Property of 1-(2-chlorophenyl)-N-[2-[(2-chlorophenyl)methylideneamino]ethyl]methanimine

Chemical Property:

• Boiling Point: 432°Cat760mmHg
• Flash Point: 215.1°C
• Density: 1.16g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(2-chlorophenyl)-N-[2-[(2-chlorophenyl)methylideneamino]ethyl]methanimine

There total 3 articles about 1-(2-chlorophenyl)-N-[2-[(2-chlorophenyl)methylideneamino]ethyl]methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2-chloro-benzaldehyde (89-98-5) + ethylenediamine (107-15-3,85404-18-8) → N,N'-(ethane-1,2-diyl)bis(1-(2-chlorophenyl)methanimine) (81512-53-0,348630-60-4)

Guidance literature:

In methanol; for 12h;

DOI:10.4314/bcse.v28i1.9

Reference yield: 85.0%

2-chloro-benzaldehyde (89-98-5) + ethylenediamine (107-15-3,85404-18-8) → N,N'-Bis(2-chlorobenzylidene)-1,2-ethanediamine (81512-53-0,348630-60-4)

Guidance literature:

In ethanol; for 0.5h; Heating;

DOI:10.1039/b008520k

Reference yield:

2-chloro-benzaldehyde (89-98-5) + ethylenediamine (107-15-3,85404-18-8) → 2,3-dihydro-1H-benzo[e][1,4]diazepine (5945-91-5) + N,N'-Bis(2-chlorobenzylidene)-1,2-ethanediamine (81512-53-0,348630-60-4)

Guidance literature:

With formic acid; copper; Yield given. Multistep reaction. Yields of byproduct given; 1.) toluene, reflux, 30 min, 2.) toluene, reflux, 4 h;

DOI:10.1055/s-1988-27721

upstream raw materials:

2-chloro-benzaldehyde

ethylenediamine

Downstream raw materials:

2,2'-bis-(2-chloro-phenyl)-2,2'-ethanediyldiamino-di-acetic acid

3,3'-(ethane-1,2-diyl)bis(2-(2-chlorophenyl)thiazolidin-4-one)

N¹-(2-chlorobenzyl)ethane-1,2-diamine

N¹,N²-bis(2-chlorobenzyl)ethane-1,2-diamine

Refernces

Bis[N,N′-(2-chloro-benzyl-idene)-ethylene-diamine-κ² N,N′]copper(I) dichlorido-cuprate(I) acetonitrile solvate

10.1107/S0108270107054960

The study focuses on the synthesis and crystal structure analysis of a copper(I) complex with an unconjugated dimine ligand, specifically the 1:1 adduct of N,N-bis(2-chlorobenzylidene)ethylenediamine (cbzen) with copper(I) chloride, resulting in the ionic compound [Cu(C16H14Cl2N2)]2][CuCl2]-CH3CN. The purpose of the study is to examine the nature of the complex formed and its coordination chemistry, which is of interest due to the potential applications of such complexes in catalytic processes, photosensitization reactions, light-harvesting studies, and the design of supramolecular arrays. The chemicals used in the study include copper(I) chloride (CuCl) as the metal halide, and N,N-bis(2-chlorobenzylidene)ethylenediamine (cbzen) as the nitrogen-based ligand. These chemicals serve to form the bis(ligand)copper(I) cation and a dichloridocuprate(I) anion, along with a molecule of acetonitrile solvent, which together constitute the crystal structure of the compound under investigation.