Ethanone, 1-phenyl-2-(2-pyridinyl)-, oxime, (Z)-

Base Information

• Chemical Name: Ethanone, 1-phenyl-2-(2-pyridinyl)-, oxime, (Z)-
• CAS No.: 61890-11-7
• Molecular Formula: C₁₃H₁₂N₂O
• Molecular Weight: 212.251
• Mol file: 61890-11-7.mol

Synonyms:HMS2300P19;Ethanone,1-phenyl-2-(2-pyridinyl)-,oxime,(Z);1-Phenyl-2-[2]pyridyl-aethanon-oxim;1-phenyl-2-[2]pyridyl-ethanone oxime;Ethanone,1-phenyl-2-(2-pyridinyl)-,oxime,(E);2-(2-Pyridyl)-acetophenonoxim;syn-2-pycolyl phenyl ketoxime;2-Phenacyl-pyridin-oxim;1-phenyl-2-(2-pyridyl)ethanal oxime;

Chemical Property of Ethanone, 1-phenyl-2-(2-pyridinyl)-, oxime, (Z)-

Chemical Property:

• PSA: 45.48000
• LogP: 2.50260

Purity/Quality:

(NZ)-N-(1-PHENYL-2-PYRIDIN-2-YLETHYLIDENE)HYDROXYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethanone, 1-phenyl-2-(2-pyridinyl)-, oxime, (Z)-

There total 1 articles about Ethanone, 1-phenyl-2-(2-pyridinyl)-, oxime, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1-phenyl-2-(2-pyridyl)ethanal oxime (61890-11-7)

Guidance literature:

2-Phenacyl-pyridin (I), Hydroxylamin-hydrochlorid, wss. NaOH, in A.;

DOI:10.1021/jo01053a010

Reference yield: 31.0%

1-phenyl-2-(2-pyridyl)ethanal oxime (61890-11-7) → 3-phenyl-2-(2-pyridyl)-2H-aziridine

Guidance literature:

With triethylamine; p-toluenesulfonyl chloride; In dichloromethane; for 24h;

Reference yield:

1-phenyl-2-(2-pyridyl)ethanal oxime (61890-11-7) → 3-phenylimidazo[1,5-a]pyridine (35854-46-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 31 percent / TsCl, NEt₃ / CH₂Cl₂ / 24 h

2: 50 percent / acetone / 2 h / Irradiation

With triethylamine; p-toluenesulfonyl chloride; In dichloromethane; acetone;

Downstream raw materials:

3-phenylimidazo[1,5-a]pyridine

monohydrogen-bis(syn-2-pycolyl phenyl ketoxime)copper(II)Cl

monohydrogen-bis(syn-2-pycolyl phenyl ketoxime)copper(II)NO₃

monohydrogen-bis(syn-2-pycolyl phenyl ketoxime)copper(II)Br