Benzene, 1-Methoxy-2-nitroso-

Base Information

• Chemical Name: Benzene, 1-Methoxy-2-nitroso-
• CAS No.: 17075-26-2
• Molecular Formula: C7H7 N O2
• Molecular Weight: 137.138
• Mol file: 17075-26-2.mol

Synonyms:Anisole,o-nitroso- (6CI,8CI); 2-Methoxynitrosobenzene; 2-Nitrosoanisole; NSC 227940;o-Methoxynitrosobenzene; o-Nitrosoanisole

Chemical Property of Benzene, 1-Methoxy-2-nitroso-

Chemical Property:

• Vapor Pressure: 0.0704mmHg at 25°C
• Boiling Point: 237°Cat760mmHg
• Flash Point: 117.1°C
• PSA: 38.66000
• Density: 1.1g/cm³
• LogP: 2.09310

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1-Methoxy-2-nitroso-

There total 10 articles about Benzene, 1-Methoxy-2-nitroso- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-methoxy-phenylamine (90-04-0) → 2-nitrosoanisole (17075-26-2)

Guidance literature:

With dihydrogen peroxide; In methanol; water; at 20 ℃; for 2h; chemoselective reaction; Catalytic behavior; Sealed tube;

DOI:10.1002/adsc.201500957

Reference yield: 52.0%

(2-methoxy-phenyl)-trimethyl-silane (704-43-8) → 2-nitrosoanisole (17075-26-2)

Guidance literature:

With nitrosonium tetrafluoroborate; In acetonitrile; at 20 ℃; for 0.0833333h;

DOI:10.1021/acs.joc.8b00262

Reference yield:

2-Methoxyphenylboronic acid (5720-06-9) → 2-Nitroanisole (91-23-6) + 2-nitrosoanisole (17075-26-2)

Guidance literature:

With chloro-trimethyl-silane; sodium nitrite; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1016/j.tetlet.2014.01.138

upstream raw materials:

N-(2-methoxyphenyl)hydroxylamine

2-methoxy-phenylamine

2-trimethylstannylanisole

2-Nitroanisole

Downstream raw materials:

(Z)-1,2-bis(2-methoxyphenyl)diazene 1-oxide

2.2'-dimethoxy-seqtrans-azoxybenzene

[1,2]benzoquinone monooxime

1-amino-2-methoxy-4-(N-phenylamino)benzene