2,2'-DIMETHOXYAZOXYBENZENE

Base Information

• Chemical Name: 2,2'-DIMETHOXYAZOXYBENZENE
• CAS No.: 13620-57-0
• Molecular Formula: C14H14N2O3
• Molecular Weight: 258.277
• Mol file: 13620-57-0.mol

Synonyms:bis(2-methoxyphenyl)-diazene;2,2'-dimethoxyazoxybenzene;Bis-(2-methoxy-phenyl)-diazen-N-oxid;2.2'-Dimethoxy-azoxybenzol;o.o'-Azoxyanisol;Diazene, bis(2-methoxyphenyl)-, 1-oxide;bis-(2-methoxy-phenyl)-diazene-N-oxide;Diazene,bis(2-methoxyphenyl)-,1-oxide;1,2-Bis(2-methoxyphenyl)diazene 1-oxide;

Chemical Property of 2,2'-DIMETHOXYAZOXYBENZENE

Chemical Property:

• PSA: 59.57000
• LogP: 4.15270

Purity/Quality:

98% ^*data from raw suppliers

2,2'-AZOXYANISOLE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2'-DIMETHOXYAZOXYBENZENE

There total 42 articles about 2,2'-DIMETHOXYAZOXYBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-methoxy-phenylamine (90-04-0) → 2,2'-dimethoxyazoxybenzene (13620-57-0)

Guidance literature:

With dihydrogen peroxide; In ethanol; water; at 20 ℃; for 2h;

Reference yield: 95.0%

methanol (67-56-1) + 2-Chloronitrobenzene (88-73-3) → 2,2'-dimethoxyazoxybenzene (13620-57-0)

Guidance literature:

With copper(l) iodide; sodium methylate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 10h; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.10.140

Reference yield: 92.0%

2-Nitroanisole (91-23-6) → 2,2'-dimethoxyazoxybenzene (13620-57-0)

Guidance literature:

With oxygen; ammonium chloride; zinc; In [bmim][BF₄]; water; at 20 ℃; for 18h;

DOI:10.1016/j.tetlet.2009.02.122

upstream raw materials:

methanol

1-ethoxy-2-nitrobenzene

2-Nitroanisole

sodium methylate

Downstream raw materials:

3,3'-dimethoxy-(1,1'-biphenyl)-4,4'-diamine

2-methoxy-phenylamine

N,N'-bis-(2-methoxy-phenyl)-hydrazine

sudan red G

Refernces

• 1、 -. "Preparation of niobium or tantalum complex and application of niobium or tantalum complex in catalyzing aromatic amine to generate oxidized azobenzene compound". Paragraph 0064-0067. . Retrieved 2021/11/03.
• 2、 Yan, Ziqiang,Xie, Xiaoyu,Song, Qun,Ma, Fulei,Sui, Xinyu,Huo, Ziyu,Ma, Mingming. "Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters". supporting information. p. 1301 - 1307. Retrieved 2020/03/11.