triphenyl-[(Z)-2-phenylethenyl]stannane

Base Information

Chemical Name:triphenyl-[(Z)-2-phenylethenyl]stannane
CAS No.:15799-66-3
Molecular Formula:C₂₆H₂₂Sn
Molecular Weight:453.171
Hs Code.:
NSC Number:51019
Mol file:15799-66-3.mol

Synonyms:NSC51019;NSC-51019;15799-66-3

Suppliers and Price of triphenyl-[(Z)-2-phenylethenyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of triphenyl-[(Z)-2-phenylethenyl]stannane

Chemical Property:

Vapor Pressure:5.18E-10mmHg at 25°C
Boiling Point:509.9°Cat760mmHg
Flash Point:261°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:454.074353
Heavy Atom Count:27
Complexity:397

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C=C[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4
Isomeric SMILES:C1=CC=C(C=C1)/C=C\[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of triphenyl-[(Z)-2-phenylethenyl]stannane

There total 6 articles about triphenyl-[(Z)-2-phenylethenyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 892-20-6
triphenylstannane

: 536-74-3
phenylacetylene

: 15799-66-3,57682-80-1,17421-59-9
(E/Z)-β-triphenylstyriltin

Guidance literature:: In not given;

Reference yield: 75.0%

: 892-20-6
triphenylstannane

: 536-74-3
phenylacetylene

: 15799-66-3,17421-59-9,57682-80-1
trans-β-triphenylstannylstyrene

Guidance literature:: triethyl borane; In hexane; toluene; addn. of Et3B in hexane to a soln. of PhCCH and Ph3SnH in toluene at 25°C under Ar, stirring for 20 min; pouring into water, extg. 3 times with ethyl acetate, washing the combined org. layers with brine, drying over Na2SO4, concg. in vac., preparative TLC on silica gel;
DOI:10.1021/ja00242a068

Reference yield: 61.0%

: 892-20-6
triphenylstannane

: 536-74-3
phenylacetylene

: 15799-66-3,17421-59-9,57682-80-1
(Z)-1-phenyl-2-triphenylstannylethene

Guidance literature:: In tetrahydrofuran; Sonication; sonochemical irradiation of a mixt. of Ph3SnH and phenylacetylene in THF with 10 mol % AIBN under argon, 1.5h (-55 °C internal temp.);; 87 % cis selectivity;;
DOI:10.1021/ja00199a059