Triphenyltin hydride

Base Information

• Chemical Name: Triphenyltin hydride
• CAS No.: 892-20-6
• Molecular Formula: C18H16 Sn
• Molecular Weight: 351.035
• Hs Code.: 2931900090
• European Community (EC) Number: 212-967-8
• UNII: 95T92AGN0V
• DSSTox Substance ID: DTXSID40893312
• Wikipedia: Triphenyltin_hydride
• Mol file: 892-20-6.mol

Synonyms:stannane, triphenyl-;tin, triphenyl-, hydride;triphenylstannane;triphenylstannyl hydride;triphenyltin;triphenyltin hydride

Chemical Property of Triphenyltin hydride

Chemical Property:

• Melting Point: 28 °C(lit.)
• Refractive Index: n20/D 1.632(lit.)
• Boiling Point: 163-165 °C0.3 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 0.00000
• Density: 1.374 g/mL at 25 °C(lit.)
• LogP: 1.93510
• Storage Temp.: 0-6°C
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 351.019578
• Heavy Atom Count: 19
• Complexity: 202

Purity/Quality:

96% 1H NMR ^*data from raw suppliers

Triphenyltin hydride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 23/24/25-50/53
• Safety Statements: 26-27-28-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)C3=CC=CC=C3
• Uses: Although the triphenyltins exhibit some curative effect, they are used mainly as protectants for control of a range of diseases, examples being early and late blights of potato and leaf spots on sugar beet and peanut.

Technology Process of Triphenyltin hydride

There total 29 articles about Triphenyltin hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methoxytriphenylstannane (1091-26-5) + diborane (19287-45-7) → triphenylstannane (892-20-6)

Guidance literature:

In pentane; reaction at -78°C;;

Reference yield: 94.0%

lithium aluminium tetrahydride (16853-85-3) + triphenyltin chloride (639-58-7) → triphenylstannane (892-20-6)

Guidance literature:

In diethyl ether; at 0 ℃; for 4h; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1246/bcsj.20210110

Reference yield: 82.0%

sodium tetrahydroborate (16940-66-2) + triphenyltin chloride (639-58-7) → triphenylstannane (892-20-6)

Guidance literature:

In diethylene glycol;

DOI:10.1016/S0022-328X(00)83743-2

upstream raw materials:

triphenyltin chloride

testosterone

di(4-isocyanatophenyl)methane

triphenyltin bromide

Downstream raw materials:

{2-(4-pyridyl)ethyl}triphenyltin

(phenethyl)triphenylstannane

hexa-Sn-phenyl-Sn,Sn'-(2,5-dimethyl-hexanediyl)-bis stannane

N-(3-triphenylstannyl-propyl)-acetamide

Refernces

• 1、 Tamborski, C.,Soloski, E. J.. "". . p. 3734 - 3734. Retrieved 1961.
• 2、 Pichler, Johann,Torvisco, Ana,Bottke, Patrick,Wilkening, Martin,Uhlig, Frank. "Novel amino propyl substituted organo tin compounds". . p. 565 - 573. Retrieved 2014/06/10.
• 3、 Keliher, Edmund J.,Burrell, Richard C.,Chobanian, Harry R.,Conkrite, Karina L.,Shukla, Rajesh,Baldwin, John E.. "Efficient syntheses of four stable-isotope labeled (1R)-menthyl (1S,2S)-(+)-2-phenylcyclopropanecarboxylates". . p. 2777 - 2784. Retrieved 2008/09/16.