Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl-

Base Information

• Chemical Name: Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl-
• CAS No.: 62875-10-9
• Molecular Formula: C10H18O3
• Molecular Weight: 186.251
• DSSTox Substance ID: DTXSID70450033
• Nikkaji Number: J964.018E
• Mol file: 62875-10-9.mol

Synonyms:Geranioldioxyd;62875-10-9;Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl-;DTXSID70450033;3,7-Dimethyl-2,3:6,7-diepoxy-1-octanol

Chemical Property of Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl-

Chemical Property:

• XLogP3: 0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 186.125594432
• Heavy Atom Count: 13
• Complexity: 214

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C(O1)CCC2(C(O2)CO)C)C

Technology Process of Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl-

There total 12 articles about Oxiranemethanol, 3-[2-(3,3-dimethyloxiranyl)ethyl]-3-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Geraniol (106-24-1) → 2,3,6,7-bis-epoxygeraniol (62875-10-9) + 3,7-dimethyl-2,6-octadienal (141-27-5,96680-15-8)

Guidance literature:

With bis(acetylacetonate)oxovanadium; 2,2'-azobis(isobutyronitrile); oxygen; 2-methyl-3-ethoxycarbonyl-5-ethylidene-4,5-dihydrofuran; In benzene; at 60 ℃; for 18h;

DOI:10.1016/S0040-4020(97)10135-1

Reference yield: 23.0%

Geraniol (106-24-1) → 2,3,6,7-bis-epoxygeraniol (62875-10-9) + [3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl]methanol (50727-94-1) + (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-ol (40036-54-2)

Guidance literature:

With 3,3-dimethyldioxirane; at 0 ℃;

DOI:10.1016/S0040-4039(00)61350-3

Reference yield:

Geraniol (106-24-1) → 2,3,6,7-bis-epoxygeraniol (62875-10-9) + [3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl]methanol (50727-94-1)

Guidance literature:

With dihydrogen peroxide; In methanol; water; at 59.84 ℃; for 1.5h;

DOI:10.1002/cplu.201200246

upstream raw materials:

Geraniol

Nerol

geraniol