(E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl-

Base Information

• Chemical Name: (E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl-
• CAS No.: 14563-31-6
• Molecular Formula: C16H16 Br N
• Molecular Weight: 302.2089
• NSC Number: 269898
• Nikkaji Number: J1.918.153G,J925.339D
• Mol file: 14563-31-6.mol

Synonyms:2844-19-1;(E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl-;4-[(E)-2-(4-bromophenyl)ethenyl]-N,N-dimethyl-aniline;NSC269898;SCHEMBL2011431;SCHEMBL2011433;4-[(E)-2-(4-bromophenyl)ethenyl]-N,N-dimethylaniline;OJAOHXMMLZIIOY-ONEGZZNKSA-N;4-(Dimethylamino)-4'-bromostilbene;NSC-269898;(E)-4-(4-bromostyryl)-N,N-dimethylaniline;(E)-N,N-Dimethyl-4'-bromostilben-4-amine;{4-[2-(4-Bromo-phenyl)-vinyl]-phenyl}-dimethyl-amine;(E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N,-dimethyl;14563-31-6

Chemical Property of (E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl-

Chemical Property:

• Vapor Pressure: 5.79E-07mmHg at 25°C
• Boiling Point: 411°Cat760mmHg
• Flash Point: 202.3°C
• Density: 1.332g/cm³
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 301.04661
• Heavy Atom Count: 18
• Complexity: 258

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C1=CC=C(C=C1)C=CC2=CC=C(C=C2)Br
• Isomeric SMILES: CN(C)C1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)Br

Technology Process of (E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl-

There total 3 articles about (E)-4-(2-(4-Bromophenyl)ethenyl)benzenamine, N,N-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

diethyl (4-bromobenzyl)phosphonate (38186-51-5) + 4-dimethylamino-benzaldehyde (100-10-7) → 4-dimethylamino-4'-bromide-stilbene (14563-31-6)

Guidance literature:

With sodium methylate; In N,N-dimethyl-formamide; at 25 ℃; for 24h;

DOI:10.1002/cmdc.200900440

Reference yield: 60.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + C14H12BrN → 4-dimethylamino-4'-bromide-stilbene (14563-31-6)

Guidance literature:

With sodium cyanoborohydride; acetic acid; at 20 ℃;

DOI:10.1021/jacs.1c05470

Reference yield:

4-dimethylamino-benzaldehyde (100-10-7) + 2-(4-bromophenyl)-acetic acid (1878-68-8) → 4-dimethylamino-4'-bromide-stilbene (14563-31-6)

Guidance literature:

With piperidine;

upstream raw materials:

4-dimethylamino-benzaldehyde

2-(4-bromophenyl)-acetic acid

diethyl (4-bromobenzyl)phosphonate

formaldehyd

Downstream raw materials:

4-[2-(4-dimethylaminophenyl)vinyl]benzaldehyde