Boron monofluoride

Base Information

• Chemical Name: Boron monofluoride
• CAS No.: 13768-60-0
• Molecular Formula: BF
• Molecular Weight: 29.8094
• UNII: N01K2O1ZJH
• DSSTox Substance ID: DTXSID501317099
• Wikipedia: Boron_monofluoride
• Wikidata: Q4946252
• Mol file: 13768-60-0.mol

Synonyms:Boron monofluoride;Borane(1), fluoro-;13768-60-0;UNII-N01K2O1ZJH;N01K2O1ZJH;EINECS 237-383-0;Fluoroborylene;Boron fluoride (BF);BH2F;BVBRZOLXXOIMQG-UHFFFAOYSA-N;DTXSID501317099;Q4946252;B-F

Chemical Property of Boron monofluoride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 30.0077083
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B]F

Technology Process of Boron monofluoride

There total 14 articles about Boron monofluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

boron + fluorine (7782-41-4) → boron fluoride (13768-60-0) + BF4 (1276025-80-9) + boron trifluoride (7637-07-2) + boron difluoride (13842-55-2)

Guidance literature:

In solid matrix; react. laser-ablated (10-40 mJ 1064 nm laser energy per 10 ns pulse) B with F2 in argon or neon matrix at 5 K; identified by IR;

DOI:10.1021/ja1110442

Reference yield:

boron + boron trifluoride (7637-07-2) → boron fluoride (13768-60-0)

Guidance literature:

2000°C, under 1 Torr;

DOI:10.1021/ja00983a018

Reference yield:

boron trifluoride (7637-07-2) → boron fluoride (13768-60-0)

Guidance literature:

With hydrogen; In gas; dc discharge (current 50 mA) inside a Pyrex cell; room temp.; 2.5:1 mixt. of H2 and BF3 (pressure 30 mTorr); rotational sp.;

DOI:10.1016/0022-2852(89)90138-0

upstream raw materials:

chlorotrifluoromethane

Dichlorodifluoromethane

boron trifluoride

trifluoromethan

Downstream raw materials:

boron oxyfluoride

1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexadiene(2,5)

B3F5

B₁₀F₁₂

Refernces

• 1、 Light, G. C.,Herm, R. R.,Matsumoto, J. H.. "". . p. 366 - 370. Retrieved 1980.
• 2、 Timms,P.L.. "". . p. 1629 - 1632. Retrieved 1967.
• 3、 Tabacco, M. B.,Stanton, C. T.,Sardella, D. J.,Davidovits, P.. "Boron atom reactions with the halomethanes". . p. 5595 - 5601. Retrieved 1985.
• 4、 Cazzoli, G.,Cludi, L.,Esposti, C. Degli,Dore, L.. "". . p. 159 - 167. Retrieved 1989.
• 5、 Wang, Xuefeng,Andrews, Lester. "Quantum-chemical calculations and IR spectra of the (F2)MF 2 molecules (M = B, Al, Ga, In, Tl) in solid matrices: A new class of very high electron affinity neutral molecules". . p. 3768 - 3771. Retrieved 2011/04/26.