Benzoic acid, 2,2'-azobis-

Base Information

• Chemical Name: Benzoic acid, 2,2'-azobis-
• CAS No.: 635-54-1
• Molecular Formula: C14H10N2O4
• Molecular Weight: 270.244
• Hs Code.: 2927000090
• DSSTox Substance ID: DTXSID50466617
• Nikkaji Number: J1.183.317I,J36.140B,J95.732A
• Mol file: 635-54-1.mol

Synonyms:635-54-1;Benzoic acid, 2,2'-azobis-;2,2'-(Diazene-1,2-diyl)dibenzoic acid;2-[(2-carboxyphenyl)diazenyl]benzoic acid;Azobenzene-2,2'-dicarboxylic acid;azodiben-zoic acid;SCHEMBL68503;DTXSID50466617;BS-46376;(E)-2,2'-(Diazene-1,2-diyl)dibenzoic acid;E74932;249283-79-2

Chemical Property of Benzoic acid, 2,2'-azobis-

Chemical Property:

• PSA: 99.32000
• LogP: 3.49840
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 270.06405680
• Heavy Atom Count: 20
• Complexity: 361

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C(=O)O)N=NC2=CC=CC=C2C(=O)O

Technology Process of Benzoic acid, 2,2'-azobis-

There total 39 articles about Benzoic acid, 2,2'-azobis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2,2'-azobenzoic acid (635-54-1)

Guidance literature:

With peracetic acid; 2-Iodobenzoic acid; In dichloromethane; at 20 - 25 ℃; for 15h;

DOI:10.1016/j.tet.2012.07.012

Reference yield: 7.0%

ortho-nitrobenzoic acid (552-16-9,104810-18-6) → 2,2'-azobenzoic acid (635-54-1)

Guidance literature:

ortho-nitrobenzoic acid; With sodium hydroxide; zinc; In ethanol; water; at 95 ℃; for 24h;

With hydrogenchloride; In water; pH=2;

DOI:10.1021/ja504484a

Reference yield:

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2-nitroso-benzoic acid (612-27-1) + ortho-nitrobenzoic acid (552-16-9,104810-18-6) + 2,2'-azobenzoic acid (635-54-1) + 2,2'-azoxy-di-benzoic acid (573-79-5)

Guidance literature:

With [(-Ti(H₂O)(OH)-O-Ti(H₂O)(OH)-O-)*(O*-O^-)]n; dihydrogen peroxide; In methanol; at 25 ℃; for 0.75h;

DOI:10.1002/1521-3773(20010119)40:2<405::AID-ANIE405>3.0.CO;2-6

upstream raw materials:

2,2'-oxydiazenediyl-bis-benzaldehyde

2,2'-dicarboxyhydrazobenzene

ortho-nitrobenzoic acid

3-oxo-1-oxy-3H-indole-2-carboxylic acid ethyl ester

Downstream raw materials:

2-(tert-butyloxycarbonylamino)benzoic acid

1,2-bis(2-(carbomethoxy)phenyl)diazene

[Cd(2,2'-azodibenzoic acid)(4,4'-bipyridine)]

[Cd(2,2'-azodibenzoic acid)(1,3-bis(4-pyridyl)propane)]