2,2'-AZOXYDIBENZOIC ACID

Base Information

• Chemical Name: 2,2'-AZOXYDIBENZOIC ACID
• CAS No.: 573-79-5
• Molecular Formula: C14H10 N2 O5
• Molecular Weight: 286.244
• Mol file: 573-79-5.mol

Synonyms:Benzoicacid, 2,2'-azoxybis- (9CI); Benzoic acid, 2,2'-azoxydi- (6CI,7CI,8CI);2,2'-Dicarboxyazoxybenzene; Azoxybenzene-2,2'-dicarboxylic acid;o,o'-Azoxybenzenedicarboxylic acid

Chemical Property of 2,2'-AZOXYDIBENZOIC ACID

Chemical Property:

• Boiling Point: 567.4°Cat760mmHg
• Flash Point: 297°C
• PSA: 115.71000
• Density: 1.41g/cm³
• LogP: 3.53190

Purity/Quality:

99% ^*data from raw suppliers

2,2'-Azoxydibenzoic acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2'-AZOXYDIBENZOIC ACID

There total 60 articles about 2,2'-AZOXYDIBENZOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2,2'-azoxy-di-benzoic acid (573-79-5)

Guidance literature:

With dihydrogen peroxide; In methanol; at 20 ℃; for 48h; Irradiation;

DOI:10.1039/c9nj00625g

Reference yield:

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2-nitroso-benzoic acid (612-27-1) + ortho-nitrobenzoic acid (552-16-9,104810-18-6) + 2,2'-azobenzoic acid (635-54-1) + 2,2'-azoxy-di-benzoic acid (573-79-5)

Guidance literature:

With [(-Ti(H₂O)(OH)-O-Ti(H₂O)(OH)-O-)*(O*-O^-)]n; dihydrogen peroxide; In methanol; at 25 ℃; for 0.75h;

DOI:10.1002/1521-3773(20010119)40:2<405::AID-ANIE405>3.0.CO;2-6

Reference yield:

ortho-nitrobenzoic acid (552-16-9,104810-18-6) → 2,2'-azoxy-di-benzoic acid (573-79-5)

Guidance literature:

With potassium hydroxide; ethanol;

upstream raw materials:

2-Aminobenzyl alcohol

2-nitroso-benzoic acid

1,3-dihydroxy-1,3-dihydro-indol-2-one

diethyl ether

Downstream raw materials:

2,2'-azoxy-di-benzoic acid dimethyl ester

3,3'-dicarboxy-4,4'-diaminobiphenyl

2,2'-dicarboxyhydrazobenzene

Refernces

• 1、 De Carvalho, Gustavo Senra Gon?alves,Chagas, Luciano Honorato,Fonseca, Carla Grijó,De Castro, Pedro P?ssa,Sant'Ana, Ant?nio Carlos,Leit?o, Alexandre Amaral,Amarante, Giovanni Wilson. "Nb2O5 supported on mixed oxides catalyzed oxidative and photochemical conversion of anilines to azoxybenzenes". supporting information. p. 5863 - 5871. Retrieved 2019/04/17.
• 2、 Gohar, G. A.. "Synthesis, Spectral Studies and C-S Bond Fission of Some Alkyl- Diacetates". . p. 43 - 58. Retrieved 2007/10/03.