4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide

Base Information

Chemical Name:4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide
CAS No.:15500-76-2
Molecular Formula:C17H24 N2 O3 S
Molecular Weight:336.455
Hs Code.:
DSSTox Substance ID:DTXSID40422080

Synonyms:MLS003106914;DTXSID40422080;15500-76-2

Suppliers and Price of 4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide

Chemical Property:

Boiling Point:467.2°Cat760mmHg
Flash Point:236.4°C
Density:1.19g/cm³
XLogP3:3.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:336.15076381
Heavy Atom Count:23
Complexity:592

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)NN=C2CC(CC(=O)C2(C)C)(C)C
Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)N/N=C/2\CC(CC(=O)C2(C)C)(C)C

Technology Process of 4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide

There total 2 articles about 4-methyl-N-[(E)-(2,2,5,5-tetramethyl-3-oxocyclohexylidene)amino]benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 702-50-1
2,2,5,5-tetramethylcyclohexa-1,3-dione

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 15500-76-2
Dimethyl-dimedon-mono-(toluol-4-sulfonyl-hydrazon)

Guidance literature:: In ethanol; at 20 ℃; for 168h; Inert atmosphere;
DOI:10.1002/hlca.201200393

Reference yield:

: 15500-76-2
Dimethyl-dimedon-mono-(toluol-4-sulfonyl-hydrazon)

Guidance literature:: Dimethyl-dimedon, Toluol-4-sulfonyl-hydrazin (neben Dimethyl-dimedon-bis- (1c));
DOI:10.1021/jo01349a076

Reference yield:

: 15500-76-2
Dimethyl-dimedon-mono-(toluol-4-sulfonyl-hydrazon)

: 827-90-7,2259-14-5,2935-23-1,4638-92-0,10453-89-1,15259-78-6,26771-06-2,26771-11-9,705-16-8
trans-chrysanthemic acid

: 2935-23-1
cis-Chrysanthemic acid

Guidance literature:: Multi-step reaction with 4 steps

1.1: ethylene glycol; sodium / 180 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid; sodium hydrogencarbonate / dichloromethane / 40 h / 20 °C / Inert atmosphere

3.1: titanium(IV) bromide / dichloromethane / 72 h / 20 °C / Inert atmosphere

3.2: 5.5 h / -10 - 20 °C / Inert atmosphere

4.1: potassium tert-butylate / water; dimethyl sulfoxide / 2 h / 20 °C / Inert atmosphere

4.2: pH 2 / Cooling with ice

With potassium tert-butylate; sodium; titanium(IV) bromide; sodium hydrogencarbonate; ethylene glycol; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; dimethyl sulfoxide;
DOI:10.1002/hlca.201200393