Hydrazine, 1,2-dimethyl-1,2-dipropyl

Base Information

• Chemical Name: Hydrazine, 1,2-dimethyl-1,2-dipropyl
• CAS No.: 23337-88-4
• Molecular Formula: C8H20 N2
• Molecular Weight: 144.26
• DSSTox Substance ID: DTXSID80177880
• Nikkaji Number: J1.359.024I
• Wikidata: Q83048221
• Mol file: 23337-88-4.mol

Synonyms:Hydrazine, 1,2-dimethyl-1,2-dipropyl;23337-88-4;DTXSID80177880

Chemical Property of Hydrazine, 1,2-dimethyl-1,2-dipropyl

Chemical Property:

• Vapor Pressure: 1.46mmHg at 25°C
• Boiling Point: 170.6°Cat760mmHg
• PKA: 11.65±0.70(Predicted)
• Flash Point: 48.1°C
• PSA: 6.48000
• Density: 0.823g/cm³
• LogP: 1.58500
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 144.162648646
• Heavy Atom Count: 10
• Complexity: 63.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCN(C)N(C)CCC

Technology Process of Hydrazine, 1,2-dimethyl-1,2-dipropyl

There total 6 articles about Hydrazine, 1,2-dimethyl-1,2-dipropyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Propionic acid N,N'-dimethyl-N'-propionyl-hydrazide (137250-46-5) → 1,2-Dipropyl-1,2-dimethylhydrazin (23337-88-4)

Guidance literature:

With borane; In tetrahydrofuran;

DOI:10.1021/jo00830a045

Reference yield:

N,N'-Dimethylhydrazine dihydrochloride (306-37-6) + propionaldehyde (123-38-6) → 1,2-Dipropyl-1,2-dimethylhydrazin (23337-88-4)

Guidance literature:

With sodium tetrahydroborate; N,N-dimethyl-ethanamine; acetic acid; Yield given. Multistep reaction; 1.) acetnitrile, 30 min, 2.) acetonitrile, r.t.;

DOI:10.1021/ja00232a001

Reference yield:

1-(piperidin-1-yl)piperidine (6130-94-5) + 1,2-di-n-propyldimethylhydrazine cation radical (106376-61-8) → 1,2-Dipropyl-1,2-dimethylhydrazin (23337-88-4) + [1,1']Bipiperidinyl (106376-72-1)

Guidance literature:

In chloroform; benzene; at 276.9 ℃; Rate constant; Thermodynamic data; ΔG(excit); insitu ionization;

DOI:10.1021/ja00239a015

upstream raw materials:

Propionic acid N,N'-dimethyl-N'-propionyl-hydrazide

1-(piperidin-1-yl)piperidine

1,2-di-n-propyldimethylhydrazine cation radical

1,2-di-n-butyldimethylhydrazine

Downstream raw materials:

tetramethylhydrazine

1,2-di-n-propyldimethylhydrazine cation radical

N,N'-diethyl-N,N'-dimethyl-hydrazine

dimethyl-piperidin-1-yl-amine

Refernces

• 1、 Nelsen, Stephen F.,Rumack, Daniel T.,Meot-Ner (Mautner), Michael. "Kinetic Effects of an Unusually Large Neutral to Radical Cation Geometry Change. Slow Electron-Transfer Reactions between Alkylhydrazines". . p. 1373 - 1379. Retrieved 2007/10/02.