Ethyl 3-p-tolyloxirane-2-carboxylate

Base Information

Chemical Name:Ethyl 3-p-tolyloxirane-2-carboxylate
CAS No.:52788-71-3
Molecular Formula:C12H14 O3
Molecular Weight:206.241
Hs Code.:2918990090
European Community (EC) Number:258-180-3
DSSTox Substance ID:DTXSID20866281
Nikkaji Number:J184.037A
Mol file:52788-71-3.mol

Synonyms:Ethyl 3-p-tolyloxirane-2-carboxylate;52788-71-3;Ethyl 3-(4-methylphenyl)glycidate;ethyl 3-(4-methylphenyl)oxirane-2-carboxylate;3-(p-Tolyl)glycidic acid, ethyl ester;EINECS 258-180-3;Oxiranecarboxylic acid, 3-(4-methylphenyl)-, ethyl ester;2-Oxiranecarboxylic acid, 3-(4-methylphenyl)-, ethyl ester;Ethyl 3-(4-methylphenyl)-2-oxiranecarboxylate;TYJ3DG2TQR;UNII-TYJ3DG2TQR;SCHEMBL2210689;DTXSID20866281;3-(p-Tolyl)oxirane-2-carboxylic acid ethyl ester

Suppliers and Price of Ethyl 3-p-tolyloxirane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 15 raw suppliers

Chemical Property of Ethyl 3-p-tolyloxirane-2-carboxylate

Chemical Property:

Vapor Pressure:0.00198mmHg at 25°C
Boiling Point:291.2°Cat760mmHg
Flash Point:117.7°C
PSA：38.83000
Density:1.153g/cm³
LogP:1.99800
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:206.094294304
Heavy Atom Count:15
Complexity:231

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1C(O1)C2=CC=C(C=C2)C

Technology Process of Ethyl 3-p-tolyloxirane-2-carboxylate

There total 4 articles about Ethyl 3-p-tolyloxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 104-87-0
4-methyl-benzaldehyde

: 105-39-5
chloroacetic acid ethyl ester

: 52788-71-3
ethyl 3-(4-methylphenyl)oxirane-2-carboxylate

Guidance literature:: With potassium hydroxide; In tetrahydrofuran; at 24.84 ℃; for 8h;
DOI:10.1016/j.tetlet.2007.05.001

Reference yield: 42.0%

: 97585-04-1,20511-20-0,24393-49-5
ethyl (E)-3-(4-methylphenyl)acrylate

: 74087-85-7
3,3-dimethyldioxirane

: 52788-71-3
ethyl 3-(4-methylphenyl)oxirane-2-carboxylate

Guidance literature:: In acetone; Ambient temperature;
DOI:10.1039/P29900000349

Reference yield:

: 25709-55-1
1-<(ethoxycarbonyl)methyl>tetrahydrothiophenium bromide

: 104-87-0
4-methyl-benzaldehyde

: 52788-71-3
ethyl 3-(4-methylphenyl)oxirane-2-carboxylate

Guidance literature:: With potassium carbonate; Yield given. Multistep reaction; 1) CH₃CN, H₂O, 60 deg C, 15 min 2) CH₃CN, 60 min;
DOI:10.1021/jo00289a022