Silane, (1,1-dimethylethyl)[(2-fluoro-4-pentenyl)oxy]diphenyl-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)[(2-fluoro-4-pentenyl)oxy]diphenyl-
CAS No.:645413-03-2
Molecular Formula:C21H27FOSi
Molecular Weight:342.529
Hs Code.:

Synonyms:

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Chemical Property of Silane, (1,1-dimethylethyl)[(2-fluoro-4-pentenyl)oxy]diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Silane, (1,1-dimethylethyl)[(2-fluoro-4-pentenyl)oxy]diphenyl-

There total 2 articles about Silane, (1,1-dimethylethyl)[(2-fluoro-4-pentenyl)oxy]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3885-22-1
ethyl-2-fluoro-4-pentenoate

: 645413-03-2
1-(tert-butyldiphenylsilyloxy)-2-fluoropent-4-ene

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether / 18 h / 23 °C

2: 13.17 g / imidazole / dimethylformamide / 12 h

With 1H-imidazole; lithium aluminium tetrahydride; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/ja037935a

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 2-fluoro-4-penten-1-ol

: 645413-03-2
1-(tert-butyldiphenylsilyloxy)-2-fluoropent-4-ene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 12h;
DOI:10.1021/ja037935a

Reference yield:

: 645413-03-2
1-(tert-butyldiphenylsilyloxy)-2-fluoropent-4-ene

: 645413-08-7
5-fluoro-2-benzyloxytetrahydropyran

Guidance literature:: Multi-step reaction with 5 steps

1.1: BH₃*SMe₂ / tetrahydrofuran / 72 h / 23 °C

1.2: 83 percent / aq. H₂O₂; NaOH / tetrahydrofuran / 48 h / 23 °C

2.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 16 h

3.1: 86 percent / p-toluenesulfonic acid monohydrate / benzene / 20 h / 80 °C

4.1: 86 percent / tetrabutylammonium fluoride / tetrahydrofuran / 23 h / 20 °C

5.1: 81 percent / p-toluenesulfonic acid monohydrate / CH₂Cl₂ / 17 h / 0 °C

With dimethylsulfide borane complex; tetrabutyl ammonium fluoride; Dess-Martin periodane; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; benzene; 2.1: Dess-Martin oxidation;
DOI:10.1021/ja037935a