Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]-
CAS No.:646038-59-7
Molecular Formula:C17H30O3SSi
Molecular Weight:342.575
Hs Code.:
DSSTox Substance ID:DTXSID20401656

Synonyms:646038-59-7;Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]-;DTXSID20401656;FT-0664083

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:8
Exact Mass:342.16849252
Heavy Atom Count:22
Complexity:426

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CCS(=O)(=O)C1=CC=CC=C1)CO[Si](C)(C)C(C)(C)C

Technology Process of Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]-

There total 3 articles about Silane, (1,1-dimethylethyl)dimethyl[2-methyl-4-(phenylsulfonyl)butoxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 129518-66-7
(R,S)-4-(phenylsulfonyl)-2-methyl-1-butanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 646038-59-7
(4-benzenesulfonyl-2-methyl-butoxy)-tert-butyldimethylsilane

Guidance literature:: With 1H-imidazole; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/S0039-128X(03)00116-8

Reference yield:

: 873-55-2
sodium benzenesulfonate

: 646038-59-7
(4-benzenesulfonyl-2-methyl-butoxy)-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 5 steps

1: 99 percent / KH₂PO₄ / H₂O / 48 h / 20 °C

2: 70 percent / n-BuLi / tetrahydrofuran; hexane / 0.33 h / 0 °C

3: perchloric acid / tetrahydrofuran; H₂O / 2 h / Heating

4: 3.2 g / NaBH₄ / methanol / 0 - 20 °C

5: 90 percent / imidazole / tetrahydrofuran / 20 °C

With 1H-imidazole; sodium tetrahydroborate; potassium dihydrogenphosphate; n-butyllithium; perchloric acid; In tetrahydrofuran; methanol; hexane; water; 2: Wittig reaction;
DOI:10.1016/S0039-128X(03)00116-8

Reference yield:

: 646038-58-6
(4-methoxy-3-methyl-but-3-ene-1-sulfonyl)benzene

: 646038-59-7
(4-benzenesulfonyl-2-methyl-butoxy)-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: perchloric acid / tetrahydrofuran; H₂O / 2 h / Heating

2: 3.2 g / NaBH₄ / methanol / 0 - 20 °C

3: 90 percent / imidazole / tetrahydrofuran / 20 °C

With 1H-imidazole; sodium tetrahydroborate; perchloric acid; In tetrahydrofuran; methanol; water;
DOI:10.1016/S0039-128X(03)00116-8