1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane

Base Information

• Chemical Name: 1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane
• CAS No.: 648898-32-2
• Molecular Formula: C₁₇H₂₇Br₃O₆
• Molecular Weight: 567.11
• Hs Code.: 2915900090
• Mol file: 648898-32-2.mol

Synonyms:Trifunctional initiator;3f-BiB;

Chemical Property of 1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane

Chemical Property:

• Melting Point: 54-60°C
• Boiling Point: 519.8±45.0 °C(Predicted)
• Flash Point: >110℃
• PSA: 78.90000
• Density: 1.578±0.06 g/cm3(Predicted)
• LogP: 4.14280

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Atom Transfer Radical Polymerization (ATRP) initiator for the creation of trifunctional polymers.Polymerization will occur at three sites creating a three-arm star polymer.

Technology Process of 1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane

There total 1 articles about 1,1,1-Tris(2-bromoisobutyryloxymethyl)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

2-(hydroxymethyl)-2-methylpropane-1,3-diol (77-85-0) + 2-bromoisobutyric acid bromide (20769-85-1) → 1,1,1-tris(2-bromoisobutyryloxymethyl)ethane (648898-32-2)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/ma500391z

upstream raw materials:

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-bromoisobutyric acid bromide

Refernces

• 1、 Jeong, Jonghwa,Kim, Kihyun,Lee, Rooda,Lee, Sookyeong,Kim, Hyewon,Jung, Haeji,Kadir, Mohammad Abdul,Jang, Yujin,Jeon, Heung Bae,Matyjaszewski, Krzysztof,Chang, Taihyun,Paik, Hyun-Jong. "Preparation and analysis of bicyclic polystyrene". . p. 3791 - 3796. Retrieved 2014/07/08.