Methyl 4-(2-methylbenzoyl)benzoate

Base Information

Chemical Name:Methyl 4-(2-methylbenzoyl)benzoate
CAS No.:649756-96-7
Molecular Formula:C16H14O3
Molecular Weight:254.285
Hs Code.:
DSSTox Substance ID:DTXSID70466230
Wikidata:Q82292748

Synonyms:Methyl 4-(2-methylbenzoyl)benzoate;649756-96-7;Benzoic acid, 4-(2-methylbenzoyl)-, methyl ester;SCHEMBL1774122;DTXSID70466230;RJABMTXFRBDXQN-UHFFFAOYSA-N;FT-0747243

Suppliers and Price of Methyl 4-(2-methylbenzoyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Methyl 4-(2-methylbenzoyl)benzoate

Chemical Property:

XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:254.094294304
Heavy Atom Count:19
Complexity:329

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1C(=O)C2=CC=C(C=C2)C(=O)OC

Technology Process of Methyl 4-(2-methylbenzoyl)benzoate

There total 6 articles about Methyl 4-(2-methylbenzoyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1679-64-7
Monomethyl terephthalate

: 108-88-3,15644-74-3,16713-13-6
toluene

: 64141-11-3
(4-(methoxycarbonyl)phenyl)(4-methylphenyl)methanone

: 649756-96-7
4-(2-methylbenzoyl)benzoic acid methyl ester

Guidance literature:: With Methanesulfonic anhydride; at 102 ℃; for 2h;
DOI:10.1021/ol200482s

Reference yield: 46.0%

: 529-20-4
2-methylphenyl aldehyde

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 649756-96-7
4-(2-methylbenzoyl)benzoic acid methyl ester

Guidance literature:: With tetrakis(triphenylphosphine)nickel⁽⁰⁾; acetone; 1,2-bis-(dicyclohexylphosphino)ethane; In dimethyl sulfoxide; at 120 ℃; for 12h; Inert atmosphere; Sealed tube; Schlenk technique; Molecular sieve; Glovebox;
DOI:10.1021/acs.orglett.9b01782

Reference yield: 44.0%

: 95-46-5
2-methylphenyl bromide

: 7377-26-6
4-Methoxycarbonylbenzoyl chloride

: 649756-96-7
4-(2-methylbenzoyl)benzoic acid methyl ester

Guidance literature:: 2-methylphenyl bromide; With magnesium; In diethyl ether; benzene; for 0.333333h; Heating;

With cadmium(II) chloride; In diethyl ether; benzene; for 0.75h; Heating;

4-Methoxycarbonylbenzoyl chloride; In diethyl ether; benzene; for 3h; Heating;
DOI:10.1021/jo048055x