4,6,10-Dodecatrienoic acid, 2,2,7,11-tetramethyl-3-[(trimethylsilyl)oxy]-, methyl ester, (6E)-

Base Information

Chemical Name:4,6,10-Dodecatrienoic acid, 2,2,7,11-tetramethyl-3-[(trimethylsilyl)oxy]-, methyl ester, (6E)-
CAS No.:649772-12-3
Molecular Formula:C20H36O3Si
Molecular Weight:362.616
Hs Code.:

Synonyms:

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Chemical Property of 4,6,10-Dodecatrienoic acid, 2,2,7,11-tetramethyl-3-[(trimethylsilyl)oxy]-, methyl ester, (6E)-

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 4,6,10-Dodecatrienoic acid, 2,2,7,11-tetramethyl-3-[(trimethylsilyl)oxy]-, methyl ester, (6E)-

There total 1 articles about 4,6,10-Dodecatrienoic acid, 2,2,7,11-tetramethyl-3-[(trimethylsilyl)oxy]-, methyl ester, (6E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 17082-61-0
1,2-bis(trimethylsiloxy)cyclobutene

: 104-55-2
3-phenyl-propenal

: 649772-12-3
2-((E)-3-Phenyl-1-trimethylsilanyloxy-allyl)-2-trimethylsilanyloxy-cyclobutanone

Guidance literature:: magnesium iodide; In dichloromethane; benzene; at 22 ℃; for 0.5h;
DOI:10.1021/ol026585e

Reference yield: 93.0%

: 649772-12-3
2-((E)-3-Phenyl-1-trimethylsilanyloxy-allyl)-2-trimethylsilanyloxy-cyclobutanone

: 5-((E)-3-Phenyl-1-trimethylsilanyloxy-allyl)-5-trimethylsilanyloxy-dihydro-furan-2-one

Guidance literature:: With peracetic acid; sodium acetate; In chloroform; at 70 ℃; for 3h; optical yield given as %de; diastereoselective reaction;
DOI:10.1080/00397911.2010.527421

Reference yield:

: 649772-12-3
2-((E)-3-Phenyl-1-trimethylsilanyloxy-allyl)-2-trimethylsilanyloxy-cyclobutanone

: 6-((E)-Styryl)-dihydro-pyran-2,5-dione

Guidance literature:: Multi-step reaction with 2 steps

1.1: trifluoroacetic acid / tetrahydrofuran; H₂O

1.2: p-toluenesulfonic acid / benzene / 80 °C

With trifluoroacetic acid; In tetrahydrofuran; water;
DOI:10.1021/ol026585e