15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-

Base Information

Chemical Name:15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-
CAS No.:651321-36-7
Molecular Formula:C30H44O5
Molecular Weight:484.676
Hs Code.:
DSSTox Substance ID:DTXSID80466004
Nikkaji Number:J1.988.325F

Synonyms:651321-36-7;15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-;DTXSID80466004

Suppliers and Price of 15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-

Chemical Property:

XLogP3:6.2
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:20
Exact Mass:484.31887450
Heavy Atom Count:35
Complexity:501

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=CCCCCCCCCCC(C(C(C(CO)O)OCC1=CC=CC=C1)OCC2=CC=CC=C2)O
Isomeric SMILES:C=CCCCCCCCCC[C@@H]([C@H]([C@@H]([C@@H](CO)O)OCC1=CC=CC=C1)OCC2=CC=CC=C2)O

Technology Process of 15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)-

There total 5 articles about 15-Hexadecene-1,2,5-triol, 3,4-bis(phenylmethoxy)-, (2R,3R,4R,5S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 651321-35-6
(2R,3R,4R,5S)-1-[(1,1-dimethylethyl)(dimethyl)silyloxy]-3,4-bis(phenylmethyloxy)hexadec-15-ene-2,5-diol

: 651321-36-7
(2R,3R,4R,5S)-3,4-bis(phenylmethyloxy)hexadec-15-ene-1,2,5-triol

Guidance literature:: With hydrogenchloride; In methanol; at 0 ℃; for 3h;
DOI:10.1081/CAR-120026470

Reference yield:

: 88476-93-1
10-undecen-1-ylmagnesium bromide

: 651321-36-7
(2R,3R,4R,5S)-3,4-bis(phenylmethyloxy)hexadec-15-ene-1,2,5-triol

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 3 h / 20 °C

2: 86 percent / HCl / methanol / 3 h / 0 °C

With hydrogenchloride; In tetrahydrofuran; methanol; 1: Grignard addition;
DOI:10.1081/CAR-120026470

Reference yield:

: 138535-75-8
2,3-di-O-benzyl-D-arabinose diethyl dithioacetal

: 651321-36-7
(2R,3R,4R,5S)-3,4-bis(phenylmethyloxy)hexadec-15-ene-1,2,5-triol

Guidance literature:: Multi-step reaction with 4 steps

1: 87 percent / imidazole / dimethylformamide / 12 h / 20 °C

2: HgO; HgCl₂ / acetone; H₂O / 3 h / 60 °C

3: tetrahydrofuran / 3 h / 20 °C

4: 86 percent / HCl / methanol / 3 h / 0 °C

With 1H-imidazole; hydrogenchloride; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; acetone; 3: Grignard addition;
DOI:10.1081/CAR-120026470