1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)-

Base Information

Chemical Name:1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)-
CAS No.:652980-00-2
Molecular Formula:C12H18O10P2
Molecular Weight:384.216
Hs Code.:

Synonyms:

Suppliers and Price of 1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)-

Chemical Property:

Purity/Quality:

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Technology Process of 1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)-

There total 10 articles about 1,3-Dioxane-4-methanol, 5-methyl-2-phenyl-5-(phosphonooxy)-, dihydrogen phosphate, (2S,4R,5S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 652979-99-2
1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(dibenzylphosphate)

: 652980-00-2
1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(phosphoric acid monoester)

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; at -10 ℃; for 1h; under 760 Torr;
DOI:10.1021/ol0362562

Reference yield:

: 81577-58-4
1,3-(R)-O-benzylidene-D-threitol

: 652980-00-2
1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(phosphoric acid monoester)

Guidance literature:: Multi-step reaction with 7 steps

1.1: 84 percent / Et₃N; 4-dimethylaminopyridine / dimethylformamide / 0.67 h / 20 °C

2.1: 86 percent / NaIO₄; K₂CO₃; benzyltriethylammonium chloride / RuO₂ / CCl₄; H₂O / 16 h / 20 °C

3.1: 75 percent / diethyl ether / 0.5 h / -78 °C

4.1: 96 percent / Bu₄NF / tetrahydrofuran / 0.28 h / 0 - 20 °C

5.1: tetrazole / tetrahydrofuran / 0.5 h / 20 °C

5.2: tetrahydrofuran / 0.52 h / 20 °C

6.1: 257 mg / mCPBA / tetrahydrofuran / 0 - 20 °C

7.1: H₂ / Pc/C / methanol / 1 h / -10 °C / 760 Torr

With 1H-tetrazole; dmap; sodium periodate; tetrabutyl ammonium fluoride; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; ruthenium(IV) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; water; N,N-dimethyl-formamide; 3.1: Grignard addition;
DOI:10.1021/ol0362562

Reference yield:

: 100-52-7
benzaldehyde

: 652980-00-2
1,3-O-benzylidene-2-C-methyl-D-erythritol 2,4-bis(phosphoric acid monoester)

Guidance literature:: Multi-step reaction with 10 steps

1.1: 80 percent / HCl / 18 h / 20 °C

2.1: NaHCO₃; NaIO₄ / CH₂Cl₂ / 1 h / 0 - 20 °C

3.1: 1.94 g / NaBH₄ / methanol / 0.5 h / 20 °C

4.1: 84 percent / Et₃N; 4-dimethylaminopyridine / dimethylformamide / 0.67 h / 20 °C

5.1: 86 percent / NaIO₄; K₂CO₃; benzyltriethylammonium chloride / RuO₂ / CCl₄; H₂O / 16 h / 20 °C

6.1: 75 percent / diethyl ether / 0.5 h / -78 °C

7.1: 96 percent / Bu₄NF / tetrahydrofuran / 0.28 h / 0 - 20 °C

8.1: tetrazole / tetrahydrofuran / 0.5 h / 20 °C

8.2: tetrahydrofuran / 0.52 h / 20 °C

9.1: 257 mg / mCPBA / tetrahydrofuran / 0 - 20 °C

10.1: H₂ / Pc/C / methanol / 1 h / -10 °C / 760 Torr

With 1H-tetrazole; hydrogenchloride; dmap; sodium tetrahydroborate; sodium periodate; tetrabutyl ammonium fluoride; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; sodium hydrogencarbonate; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; ruthenium(IV) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; 6.1: Grignard addition;
DOI:10.1021/ol0362562