Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester

Base Information

Chemical Name:Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester
CAS No.:653584-99-7
Molecular Formula:C16H19O3P
Molecular Weight:290.29400
Hs Code.:
DSSTox Substance ID:DTXSID30461009
Nikkaji Number:J1.961.461A

Synonyms:653584-99-7;Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester;DTXSID30461009

Suppliers and Price of Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester

Chemical Property:

PSA：45.34000
LogP:3.80080
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:290.10718146
Heavy Atom Count:20
Complexity:307

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOP(=O)(COCC1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester

There total 2 articles about Phosphinic acid, phenyl[(phenylmethoxy)methyl]-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 591-50-4
iodobenzene

: 653585-12-7
ethyl benzyloxymethyl-hydrogenphosphinate

: 653584-99-7
benzyloxymethyl-phenyl-phosphinic acid ethyl ester

Guidance literature:: With triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 2.5h; Heating;
DOI:10.1055/s-2003-41045

Reference yield:

: 674789-16-3
benzyloxymethyl-hydrogenphosphinic acid

: 653584-99-7
benzyloxymethyl-phenyl-phosphinic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / toluene / 12 h / Heating

2: 70 percent / Et₃N / Pd(PPh₃)4 / toluene / 2.5 h / Heating

With triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene;
DOI:10.1055/s-2003-41045