(6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate

Base Information

Chemical Name:(6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate
CAS No.:6893-78-3
Molecular Formula:C16H22O7S
Molecular Weight:358.4067
Hs Code.:
NSC Number:170234
DSSTox Substance ID:DTXSID60305326

Synonyms:6893-78-3;NSC170234;DTXSID60305326;NSC-170234;3-O-Methyl-5-O-(4-methylbenzene-1-sulfonyl)-1,2-O-(1-methylethylidene)pentofuranose

Suppliers and Price of (6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate

Chemical Property:

Vapor Pressure:1.79E-08mmHg at 25°C
Boiling Point:467.7°Cat760mmHg
Flash Point:236.6°C
Density:1.33g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:5
Exact Mass:358.10862421
Heavy Atom Count:24
Complexity:533

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2C(C3C(O2)OC(O3)(C)C)OC

Technology Process of (6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate

There total 3 articles about (6-Methoxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 98-59-9
p-toluenesulfonyl chloride

: 190584-03-3
1,2-O-isopropylidene-3-O-methyl-β-L-arabinofuranose

: 6893-78-3
1,2-O-isopropylidene-3-O-methyl-5-O-tosyl-β-L-arabinofuranose

Guidance literature:: With pyridine; at 20 ℃; for 24h;
DOI:10.1002/ejoc.200800744

Reference yield:

: 5328-37-0
L-arabinose

: 6893-78-3
1,2-O-isopropylidene-3-O-methyl-5-O-tosyl-β-L-arabinofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogen chloride; methanol / Behandeln des Reaktionsprodukts mit Toluol-4-sulfonylchlorid und Pyridin und Behandeln des danach isolierten Reaktionsprodukts mit Chlorwasserstoff enthaltendem Aceton

2: silver oxide

With hydrogenchloride; methanol; silver(l) oxide;