Di-n-hexylsilane

Base Information

• Chemical Name: Di-n-hexylsilane
• CAS No.: 1002-78-4
• Molecular Formula: C12H28 Si
• Molecular Weight: 200.44
• NSC Number: 168689
• DSSTox Substance ID: DTXSID90905257
• Mol file: 1002-78-4.mol

Synonyms:1002-78-4;di-n-hexylsilane;NSC168689;DTXSID90905257;NSC-168689;CID 6330317

Chemical Property of Di-n-hexylsilane

Chemical Property:

• Vapor Pressure: 0.054mmHg at 25°C
• Boiling Point: 242°Cat760mmHg
• Flash Point: 100.2°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 198.180377364
• Heavy Atom Count: 13
• Complexity: 71.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[Si]CCCCCC

Technology Process of Di-n-hexylsilane

There total 3 articles about Di-n-hexylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + hexylsilane (1072-14-6) → C14H24Si (132904-50-8) + (1-hexyl)(hexyl)silane (1002-78-4)

Guidance literature:

With C₂₄BF₂₀^(1-)*C₃₇H₅₇IrNP₂Si⁽¹⁺⁾; In fluorobenzene; at 60 ℃; for 20h; Inert atmosphere;

DOI:10.1021/ja803332h

Reference yield: 37.4%

1-hexene (592-41-6,25067-06-5) → hexylsilane (1072-14-6) + (1-hexyl)(hexyl)silane (1002-78-4)

Guidance literature:

With lithium aluminium tetrahydride; monosilane; at 160 ℃; for 20h; under 22065.2 - 29420.3 Torr;

DOI:10.1246/cl.1996.1013

Reference yield: 15.0%

1-hexene (592-41-6,25067-06-5) + phenylsilane (694-53-1) → (1-hexyl)(hexyl)silane (1002-78-4) + diphenylsilane (775-12-2) + hexyl-phenyl-silane (4314-98-1)

Guidance literature:

With C₂₄BF₂₀^(1-)*C₃₇H₅₇IrNP₂Si⁽¹⁺⁾; In bromobenzene-d5; at 60 ℃; for 18h; Inert atmosphere;

DOI:10.1021/ja803332h

upstream raw materials:

1-hexene

styrene

hexylsilane

phenylsilane

Downstream raw materials:

p-benzylanizole

di-n-hexyldiethoxysilane

tri-n-hexylsilane

[(Pt(PCy3))2(μ-η2-HSiHex2)2]

Refernces

• 1、 Kobayashi, Mineo,Itoh, Masayoshi. "Hydrosilylation of olefins with monosilane in the presence of lithium aluminum hydride". . p. 1013 - 1014. Retrieved 1996.
• 2、 Calimano, Elisa,Tilley, T. Don. "Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex". supporting information; body text. p. 9226 - 9227. Retrieved 2009/02/02.