4314-98-1

Upstream product

• 592-41-6 1-hexene 
• 694-53-1 phenylsilane 
• 4050-45-7 trans-2-hexene 
• 4206-75-1 phenylchlorosilane 
• 13406-07-0 1-methylpentylmagnesiumbromide 
• 68941-76-4 1-ethylbutylmagnesium bromide 
• 872-05-9 1-Decene 
• 927-77-5 n-propylmagnesium bromide 
• 4852-26-0 3-pentylmagnesium bromide 
• 931-50-0 cyclohexylmagnesium bromide 
• 33240-34-5 cyclopentylmagnesium bromide 
• 3761-92-0 n-hexylmagnesium bromide 
• 592-76-7 1-Heptene 
• 111-66-0 oct-1-ene 

Relevant academic research and scientific papers

Mechanistic study of alkene hydrosilylation catalyzed by a β-dialdiminate cobalt(i) complex

Alkene hydrosilylation is a large-scale process that typically uses precious-metal catalysts. A new generation of highly selective catalysts is based on inexpensive metals, which may have a high-spin electronic configuration and thus may follow novel mech

Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems

A novel non-innocent ligand class, namely cationic single-centre ambiphiles, is reported in the phosphine-functionalised cationic tetrylene Ni0 complexes, [PhRDippENi(PPh3)3]+ (4 a/b (Ge) and 5 (Sn); PhRDipp={[Ph2PCH2SiR2](Dipp)N}?; R=Ph, iPr; Dipp=2,6-iPr2C6H3). The inherent electronic nature of low-coordinate tetryliumylidenes, combined with the geometrically constrained [N?E?Ni] bending angle enforced by the chelating phosphine arm in these complexes, leads to strongly electrophilic EII centres which readily bind nucleophiles, reversibly in the case of NH3. Further, the GeII centre in 4 a/b readily abstracts the fluoride ion from [SbF6]? to form the fluoro-germylene complex PhRDippGe(F)Ni(PPh3)3 9, despite this GeII centre simultaneously being a σ-donating ligand towards Ni0. Alongside the observed catalytic ability of 4 and 5 in the hydrosilylation of alkynes and alkenes, this forms an exciting introduction to a multi-talented ligand class in cationic single-centre ambiphiles.

Nickel-Catalyzed Hydrosilylation of Terminal Alkenes with Primary Silanes via Electrophilic Silicon-Hydrogen Bond Activation

We report a simple and effective nickel-based catalytic system, NiCl2·6H2O/tBuOK, for the electrophilically activated hydrosilylation of terminal alkenes with primary silanes. This protocol provides excellent performance under mild reaction conditions: ex

Thermally Stable Rare-Earth Metal Complexes Supported by Chelating Silylene Ligands

The use of N-heterocyclic silylenes (NHSi) as ligands is a rapidly developing field. However, only a handful of f-element silylene complexes have been disclosed so far. Herein, we report the synthesis and characterization of a series of thermally stable d

Method of manufacturing organic silicon compound (by machine translation)

[Problem] to efficiently producing method of an organic silicon compound. The hydrosilane compounds in the presence of the catalyst in a reaction step [a] an alkene containing an organic silicon compound which, in the reaction process, the catalyst used is iron complex compound represented by the formula. R1 And R2 C each independently1 - C6 The hydrocarbon group, which may have a substituent C1 - C12 The aromatic hydrocarbon group, or a halogen atom, R3 C each independently1 - C12 Alkyl group, or a substituent which may be C6 - C12 The aromatic hydrocarbon group, X is independently a halogen atom, C1 - C12 Alkoxy, - OC (O) R6 (R6 C is1 - C12 The hydrocarbon group), or a trialkylsilyl group which may have a C1 - C12 Hydrocarbon group, is an integer of 0 - 4 n1, is an integer of 0 - 5 n2. [Drawing] no (by machine translation)

Bench-Stable Cobalt Pre-Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond

The readily synthesized and bench-stable cobalt dichloride complex (dpephos)CoCl2 is employed as a pre-catalyst for a diversity of silane additions to unsaturated organic molecules, including the normally challenging reduction of amides to amines. With regard to hydrosilative reduction of amides even more effective and activator free catalytic systems can be generated from the bench-stable, commercially available Co(acac)2 and Co(OAc)2 with dpephos and PPh3 ligands. These systems operate under mild conditions (100 °C), with many examples of room temperature transformations, presenting a first example of mild cobalt-catalyzed hydrosilylation of amides.

Magnesium hydride alkene insertion and catalytic hydrosilylation

The dimeric β-diketiminato magnesium hydride, [(BDI)MgH]2, reacts at 80 °C with the terminal alkenes, 1-hexene, 1-octene, 3-phenyl-1-propene and 3,3-dimethyl-butene to provide the respective n-hexyl, n-octyl, 3-phenylpropyl and 3,3-dimethyl-but

Multimetallic Alkaline-Earth Hydride Cations

Reactions of dimeric β-diketiminato (BDI) magnesium and calcium hydrides with [(BDI)Mg]+[Al{OC(CF3)3}4]- provide ionic multimetallic hydride derivatives, which have been characterized by single-crysta

Preparation method and application of 2, 9-diaryl-substituted phenanthroline and 2, 9-diaryl-substituted phenanthroline iron complex

The present invention relates to a preparation method and application of 2, 9-diaryl-substituted phenanthroline and a 2, 9-diaryl-substituted phenanthroline iron complex. Specifically, the substitutedphenanthroline is prepared by Suzuki coupling reaction

A β-diketiminate manganese catalyst for alkene hydrosilylation: Substrate scope, silicone preparation, and mechanistic insight

The dimeric β-diketiminate manganese hydride compound, [(2,6-iPr2PhBDI)Mn(μ-H)]2, was prepared by treating [(2,6-iPr2PhBDI)Mn(μ-Cl)]2 with NaEt3BH. This compound was characterized by single crystal X-