Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate

Base Information

Chemical Name:Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate
CAS No.:66716-63-0
Molecular Formula:C12H14O2S
Molecular Weight:222.308
Hs Code.:
DSSTox Substance ID:DTXSID10513934

Synonyms:66716-63-0;Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate;DTXSID10513934;3-Methyl-2-phenylsulfanyl-but-2-enoic acid methyl ester

Suppliers and Price of Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate

Chemical Property:

XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:222.07145086
Heavy Atom Count:15
Complexity:248

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C(C(=O)OC)SC1=CC=CC=C1)C

Technology Process of Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate

There total 10 articles about Methyl 3-methyl-2-(phenylsulfanyl)but-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 86895-68-3
methyl 3-methyl-2-phenylsulphinylbutanoate

: 66716-63-0
methyl β-methyl-α-phenylthiocrotonate

Guidance literature:: With methanesulfonic acid; acetic anhydride; In dichloromethane;
DOI:10.1016/S0040-4039(00)81858-4

Reference yield: 39.0%

: 924-50-5
Methyl 3,3-dimethylacrylate

: 931-59-9
benzenesulfenyl chloride

: 66716-63-0
methyl β-methyl-α-phenylthiocrotonate

: 40648-65-5
methyl β-hydroxy-β-methyl-α-phenylthiobutanoate

Guidance literature:: With pyridine; In chloroform; for 6h; Product distribution; Mechanism; Heating; ohter α,β-unsaturated compounds;

Reference yield: 21.0%

: 917-54-4
methyllithium

: 96899-00-2
3,3-Bis-methylsulfanyl-2-phenylsulfanyl-acrylic acid methyl ester

: 66716-63-0
methyl β-methyl-α-phenylthiocrotonate

: 96899-41-1
(Z)-methyl 3-methylthio-2-phenylthio-2-butenoate

: 96899-40-0
(E)-methyl 3-methylthio-2-phenylthio-2-butenoate

Guidance literature:: With copper(l) iodide; n-butyllithium; thiophenol; 1.) Et₂O, 0 deg, 10 min, 2.) 0 deg C, 15 min, 3.) -78 deg C, 1 h, 4.) Et₂O, -78 deg C, 45 min, then up to RT_. within 30 min;
DOI:10.1021/ja00302a014