Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate

Base Information

Chemical Name:Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate
CAS No.:67249-03-0
Molecular Formula:C16H13BrO2
Molecular Weight:317.182
Hs Code.:
DSSTox Substance ID:DTXSID801261334

Synonyms:SCHEMBL2350832;DTXSID801261334;methyl 4-[2-(4-bromophenyl)ethenyl]benzoate;67249-03-0

Suppliers and Price of Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate

Chemical Property:

XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:316.00989
Heavy Atom Count:19
Complexity:311

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C=CC2=CC=C(C=C2)Br

Technology Process of Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate

There total 7 articles about Methyl 4-[2-(4-bromophenyl)ethenyl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 1571-08-0
methyl 4-formylbenzoate

: 67249-03-0
E-4-[2-(4-bromo-phenyl)-vinyl]-benzoic acid methyl ester

Guidance literature:: With di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; di-tert-butyl peroxide; benzoyl chloride; In chlorobenzene; at 140 ℃; for 12h; diastereoselective reaction; Inert atmosphere;
DOI:10.1039/c5ra21610a

Reference yield: 54.0%

: 1253-46-9
4-methoxycarbonylbenzyltriphenylphosphonium bromide

: 589-15-1
1-bromomethyl-4-bromobenzene

: 67249-03-0
E-4-[2-(4-bromo-phenyl)-vinyl]-benzoic acid methyl ester

Guidance literature:: With sodium hydrogencarbonate; dimethyl sulfoxide; potassium iodide; at 140 ℃; for 40h; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.06.090

Reference yield:

: 2417-72-3
Methyl 4-(bromomethyl)benzoate

: 1122-91-4
4-bromo-benzaldehyde

: 67249-03-0
E-4-[2-(4-bromo-phenyl)-vinyl]-benzoic acid methyl ester

Guidance literature:: With zinc; benzene; Erwaermen des nach der Hydrolyse erhaltenen Reaktionsprodukts in Benzol mit Acetanhydrid;
DOI:10.1021/ja01862a054