Iron(II) chloride tetrahydrofuran complex

Base Information

• Chemical Name: Iron(II) chloride tetrahydrofuran complex
• CAS No.: 70317-90-7
• Molecular Formula: C8H16Cl2FeO2
• Molecular Weight: 270.96200
• Hs Code.: 29310099
• Mol file: 70317-90-7.mol

Synonyms:

Chemical Property of Iron(II) chloride tetrahydrofuran complex

Chemical Property:

• PSA: 18.46000
• LogP: -4.40090
• Storage Temp.: Flammables area

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron(II) chloride tetrahydrofuran complex

There total 5 articles about Iron(II) chloride tetrahydrofuran complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

iron(III) chloride (7705-08-0) → dichlorobis(tetrahydrofuran)iron(II) (70317-90-7)

Guidance literature:

With THF; In chlorobenzene; FeCl3 refluxed for 2 h, solid filtered, washed with toluene, dried, in the same flask THF introduced, cooled to 0°C, stirred for 10 min, warmed to 40°C; filtered;

Reference yield: 65.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + iron(III) chloride + {(2,6-iPr2C6H3)(1-cHexenyl)N}2FePMe3 → dichlorobis(tetrahydrofuran)iron(II) (70317-90-7) + C36H52N2

Guidance literature:

at -78 - 23 ℃; for 2.5h;

DOI:10.1021/acs.inorgchem.5b02990

Reference yield: 50.0%

iron(II) chloride → dichlorobis(tetrahydrofuran)iron(II) (70317-90-7)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; N2-atmosphere; extn. of FeCl2 with THF in Soxhlet extractor; cooling, filtration, drying (vac.); elem. anal.; yield depending on source and history of FeCl2;

DOI:10.1016/S0020-1693(00)89461-X

upstream raw materials:

iron(III) chloride

tetrahydrofuran

Downstream raw materials:

[Fe((C₄H₆N₂B₂)MePh₂)2]

2,6-bis[1-(3-trifluoromethylphenylimino)ethyl]pyridyliron(II) chloride

2,6-bis[1-(3-methoxyphenylimino)ethyl]pyridyliron(II) chloride

1-(6-(N-[3-(trifluoromethyl)phenyl]ethanimidoyl)pyridin-2-yl)ethanone iron(II) chloride

Refernces