(p-Tolyl)thiophosphonoyl dichloride

Base Information

Chemical Name:(p-Tolyl)thiophosphonoyl dichloride
CAS No.:6588-16-5
Molecular Formula:C7H7Cl2PS
Molecular Weight:225.078
Hs Code.:2930909090
European Community (EC) Number:229-519-2
NSC Number:164964
DSSTox Substance ID:DTXSID40984355
Nikkaji Number:J225.204J
Wikidata:Q82971558
Mol file:6588-16-5.mol

Synonyms:(p-Tolyl)thiophosphonoyl dichloride;6588-16-5;dichloro-(4-methylphenyl)-sulfanylidene-lambda5-phosphane;(4-methylphenyl)phosphonothioic dichloride;NSC164964;SCHEMBL11513233;DTXSID40984355;EINECS 229-519-2;NSC 164964;NSC-164964;Dichloro(4-methylphenyl)phosphine sulfide

Suppliers and Price of (p-Tolyl)thiophosphonoyl dichloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (p-Tolyl)thiophosphonoyl dichloride

Chemical Property:

Vapor Pressure:0.00471mmHg at 25°C
Boiling Point:285.8°Cat760mmHg
Flash Point:126.7°C
PSA：41.90000
Density:1.37g/cm³
LogP:4.05800
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:223.9383138
Heavy Atom Count:11
Complexity:169

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(=S)(Cl)Cl

Technology Process of (p-Tolyl)thiophosphonoyl dichloride

There total 1 articles about (p-Tolyl)thiophosphonoyl dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6588-16-5
phosphonothioic dichloride, (4-methylphenyl)-(4-methyl-phenyl)-dichloro-phosphine sulfide

Guidance literature:: Toluol, 1) Phosphortrichlorid, AlCl3, 2) Schwefel, AlCl3;

Reference yield: 15.0%

: 17685-52-8
triiron dodecarbonyl

: 6588-16-5
phosphonothioic dichloride, (4-methylphenyl)-(4-methyl-phenyl)-dichloro-phosphine sulfide

: 13463-40-6,37220-42-1
iron pentacarbonyl

: Fe3(CO)9(μ-S)2

: 2CH₃C₆H₄P^(2-)*Fe₃⁽⁴⁺⁾*9CO=(CH₃C₆H₄P)2Fe₃(CO)9

: 82614-07-1
(μ3-p-tolylphosphido)(μ3-thio)tris(tricarbonyliron)

Guidance literature:: In tetrahydrofuran; (N2); educts mixt. in THF refluxed for 50 min; evapd. (vac.), extd. (CH2Cl2/pentane), evapd., chromd. (pentane), evapd. (vac.), recrystd. (pentane) at -30°C; elem. anal.;

Reference yield: 8.0%

: 10170-69-1
dimanganese decacarbonyl

: 6588-16-5
phosphonothioic dichloride, (4-methylphenyl)-(4-methyl-phenyl)-dichloro-phosphine sulfide

: 103349-53-7
nonacarbonyl-μ-[(4-methylphenyl)dithioxophosphorane-P:S,S']-dimanganese

: 103349-50-4
nonacarbonyl-μ-[(4-methylphenyl)thioxophosphane-P:P,S]-dimanganese

Guidance literature:: With Mg; In tetrahydrofuran; byproducts: MgCl2, CO; (N2), (CH3C6H4)PSCl2 in THF droped to Mg and Mn2(CO)10 in THF at 20°C over 3h, stirred for 2h; soln. removed from Mg, solvent removed in vacuo, Et2O added, stirred for 0.5h, filtered, Et2O removed in vacuo, chromy. (silica gel, n-hexane/CH2Cl2 (5/1)), crystn. at -25°C from toluene, elem. anal.;