IRON DODECACARBONYL

Base Information

• Chemical Name: IRON DODECACARBONYL
• CAS No.: 17685-52-8
• Molecular Formula: C12Fe3 O12
• Molecular Weight: 503.666
• Hs Code.: 29310099
• Mol file: 17685-52-8.mol

Synonyms:Ironcarbonyl (Fe3(CO)12) (6CI); Iron, di-m-carbonyldecacarbonyltri-, triangulo- (8CI); Di-m-carbonyldecacarbonyltri-triangulo-iron;Di-m-carbonyldecacarbonyltriiron;Dodecacarbonyl-triangulo-triiron; Dodecacarbonyltriiron;Dodecacarbonyltriiron(0); Triiron dodecacarbonyl

Chemical Property of IRON DODECACARBONYL

Chemical Property:

• Appearance/Colour: black xtl.
• Melting Point: 165 °C (dec.)(lit.)
• Flash Point: 9℃
• PSA: 242.76000
• Density: 1.990
• LogP: -2.10870
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Water Solubility.: Insoluble in water. Soluble in non polar organic solvents.

Purity/Quality:

99% ^*data from raw suppliers

Iron dodecacarbonyl (Stabilized with 5-10% methanol) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn,T
• Statements: 11-23/24/25-36/37/38-20/22-39/23/24/25-20/21/22
• Safety Statements: 16-26-28-33-36/37/39-45-7/9-24-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole. Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.

Technology Process of IRON DODECACARBONYL

There total 213 articles about IRON DODECACARBONYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

diiron nonacarbonyl (15321-51-4) + Cr(C(C6H3Me2-2,6))(CO)2(η-C5H5) → iron pentacarbonyl (13463-40-6,37220-42-1) + triiron dodecarbonyl (17685-52-8) + CrFe(μ-C(C6H4Me2-2,6))(CO)5(η-C5H5)

Guidance literature:

In tetrahydrofuran; N2, stirring for 6 h at room temp.;; evapd., dissolved in CH2Cl2/light petroleum 1/1, chromd. (alumina, CH2Cl2/light petroleum 1/1), evapd., elem. anal.;

Reference yield: 86.0%

1,1-dimethylsilacyclobutane (2295-12-7) + diiron nonacarbonyl (15321-51-4) → iron pentacarbonyl (13463-40-6,37220-42-1) + triiron dodecarbonyl (17685-52-8) + 2,2,2,2-tetracarbonyl-1,1-dimethyl-1-sila-2-ferracyclopentane (39114-08-4)

Guidance literature:

In benzene; addn. of 2 equiv. of Si-compd. to Fe-complex suspn. (held above freezingpoint), warming to 21°C, stirring (24 h); removal of Fe(CO)5 and solvent (vac.), dissoln. in hexane, crystn. (-30°C, several days), filtration off of Fe3(CO)12, evapn. of filtrate(vac., low temp.), sublimation (1E-3 Torr, 0°C); elem. anal.;

DOI:10.1039/DT9780000665

Reference yield: 84.0%

diiron nonacarbonyl (15321-51-4) + 7,7-dimethyl-7-silabicyclo[4.2.0]octa-1(6),2,4-triene (17158-47-3) → iron pentacarbonyl (13463-40-6,37220-42-1) + triiron dodecarbonyl (17685-52-8) + 1,1,1,1-tetracarbonyl-2,2-dimethyl-2-sila-1-ferraindane (60104-85-0)

Guidance literature:

In benzene; N2-atmosphere; slight excess of Si-compd., stirring (21°C, 24 h); evapn. (vac., cooling to just above freezing), dissoln. in hexane, standing at -30°C for several d, filtration off of Fe3(CO)12 (-30°C), evapn. of filtrate (low temp., vac.), distn. (0.001 Torr, probe at 0°C); elem. anal.;

DOI:10.1039/DT9760000910

upstream raw materials:

nitrosyl hexafluorophosphate

{((C₆H₅)3P)2N}⁽¹⁺⁾*{HFe₄(CO)12(CO)}^(1-)={((C₆H₅)3P)2N}{HFe₄(CO)12(CO)}

indium(III) chloride

dimethylacetylene

Downstream raw materials:

(ClC₆H₄CHCHC(O)C₆H₅)Fe(CO)3

(C₆H₅CHCHC(O)CH₃OC₆H₄)Fe(CO)3

(CH₃C₆H₄CHCHC(O)C₆H₅)Fe(CO)3

Fe(CO)3(P(C₆H₄CH₃)3)2

Refernces

• 1、 Drouin, Brian J.,Kukolich, Stephen G.. "Microwave spectra and the molecular structure of tetracarbonylethyleneiron". . p. 4023 - 4030. Retrieved 1999.
• 2、 Wu, Shu-Lin,Ding, Er-Run,Yin, Yuan-Qi,Sun, Jie. "Synthesis and expansion reaction of ferrocenylacetylene dimetal carbonyl compounds. The molecular structures of μ-FcCCHCoMo(CO)5Cp and μ3-FcCHCFeCo2(CO)9". . p. 71 - 78. Retrieved 1998.
• 3、 Roustan, J. L.,Guinot, A.,Cadiot, P.. "INSERTION D'ALLENES. VI. IDENTIFICATION DU SITE REACTIONNEL DES COMPLEXES ANIONIQUES RESULTANT DE LA REACTION D'ALLENES AVEC DES ACYL FERRATES DANS LEURS REACTIONS AVEC CERTAINS ELECTROPHILES. FORMATION DE COMPLEXES η4-TRIMETHYLENE METHANE DU FER. ISOMERISATION D'UN LIGAND η4-TR...". . p. 191 - 202. Retrieved 1980.
• 4、 Ahlgren, Markku,Pakkanen, Tuula T.,Tahvanainen, Ilpo. "MIXED-METAL CLUSTER DERIVATIVES OF Co3(μ3-CPh)(CO)9: CRYSTAL STRUCTURES OF Co3(μ3-CPh)(CO)9, HFeCo2(μ3-CPh)(CO)9, AND FeCo2(μ-AuPPh3)(μ3-CPh)(CO)9". . p. 91 - 102. Retrieved 1987.
• 5、 Franken, Andreas,McGrath, Thomas D.,Stone, F. Gordon A.. "A 10-vertex iron - Dicarbollide system formed by insertion of Fe(CO) 4J into 8-vertex [closo-1-CB7H8]_: Synthesis and reactivity studies". . p. 908 - 917. Retrieved 2008.
• 6、 Rubello, Albino,Vogel, Pierre. "Polynuclear Iron and Rhodium Complexes of 7-Oxahericene (2,3,5,6-Tetramethylidenebicycloheptan-7-one". . p. 158 - 164. Retrieved 1989.
• 7、 Herrmann, Wolfgang A.,Kellner, Juergen,Riepl, Herbert. "Wasserloesliche Metallkomplexe und Katalysatoren III. Neue wasserloesliche Metallkomplexe des sulfonierten Triphenylphosphans (TPPTS): Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Ag, Au.". . p. 103 - 128. Retrieved 1990.
• 8、 Zhang, Jie,Ding, Er-Run,Chen, Xue-Nian,Zhang, Yu-Hua,Song, Cui-Ping,Yin, Yuan-Qi,Sun, Jie. "Synthesis and reaction of new metal cluster complexes containing a WRuCoSe core". . p. 1315 - 1329. Retrieved 1999.
• 9、 Marko, Laszlo,Takacs, Janos,Papp, Sandor,Marko-Monostory, Bernadett. "". . p. L189 - L190. Retrieved 1980.
• 10、 Gatto, Elisabetta,Gervasio, Giuliana,Marabello, Domenica,Sappa, Enrico. "Oligomerisation of isopropenylacetylene in the presence of Fe3(CO)12. Crystal and molecular structure of the open-cluster isomers (see abstract)". . p. 1448 - 1454. Retrieved 2002.