{[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene

Base Information

• Chemical Name: {[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene
• CAS No.: 70882-48-3
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• DSSTox Substance ID: DTXSID70500204
• Nikkaji Number: J979.001B
• Mol file: 70882-48-3.mol

Synonyms:70882-48-3;{[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene;SCHEMBL1071379;DTXSID70500204

Chemical Property of {[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene

Chemical Property:

• PSA: 9.23000
• LogP: 3.12690
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 162.104465066
• Heavy Atom Count: 12
• Complexity: 139

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=COCC1=CC=CC=C1)C

Technology Process of {[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene

There total 8 articles about {[(2-Methylprop-1-en-1-yl)oxy]methyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

((2-methylallyloxy)methyl)benzene (5658-46-8) → (((2-methylprop-1-en-1-yl)oxy)methyl)benzene (70882-48-3)

Guidance literature:

With C₃₂H₄₆ClCoN₂O₂; phenylsilane; In benzene; at 22 ℃; Inert atmosphere;

DOI:10.1021/ja5105602

Reference yield: 64.0%

2-methyl-1-propenylbromide (3017-69-4) + benzyl alcohol (100-51-6,185532-71-2) → (((2-methylprop-1-en-1-yl)oxy)methyl)benzene (70882-48-3)

Guidance literature:

With copper(l) iodide; 3,4,7,8-Tetramethyl-o-phenanthrolin; caesium carbonate; In toluene; at 80 ℃; for 48h;

DOI:10.1021/ja034809y

Reference yield: 50.0%

→ (((2-methylprop-1-en-1-yl)oxy)methyl)benzene (70882-48-3)

Guidance literature:

upstream raw materials:

isobutyraldehyde

benzyl alcohol

3-benzyloxy-4,4-dimethyl-oxetan-2-one

2-Benzyloxy-3-hydroxy-3-methyl-butyric acid

Downstream raw materials:

((2-methylallyloxy)methyl)benzene

Diphenylmethane

benzyl alcohol