2,2-Dimethyl-6-methylidenecyclohexan-1-one

Base Information

Chemical Name:2,2-Dimethyl-6-methylidenecyclohexan-1-one
CAS No.:71268-58-1
Molecular Formula:C9H14O
Molecular Weight:138.21
Hs Code.:
DSSTox Substance ID:DTXSID60552974
Wikidata:Q82433422

Synonyms:2,2-Dimethyl-6-methylidenecyclohexan-1-one;71268-58-1;SCHEMBL4392009;DTXSID60552974

Suppliers and Price of 2,2-Dimethyl-6-methylidenecyclohexan-1-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,2-Dimethyl-6-methylidenecyclohexan-1-one

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:138.104465066
Heavy Atom Count:10
Complexity:177

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(CCCC(=C)C1=O)C

Technology Process of 2,2-Dimethyl-6-methylidenecyclohexan-1-one

There total 5 articles about 2,2-Dimethyl-6-methylidenecyclohexan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1193-47-1
2,2-dimethyl-cyclohexanone

: 71268-58-1
2,2-dimethyl-6-methylenecyclohexan-1-one

Guidance literature:: at -15 ℃;

Reference yield:

: 19980-35-9
1-trimethylsilyloxy-2-methyl-1-cyclohexene

: 71268-58-1
2,2-dimethyl-6-methylenecyclohexan-1-one

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / TiCl₄ / CH₂Cl₂ / 1 h / -23 °C

2: 98 percent / W-2 Raney nickel / acetone; ethanol / 2 h / 20 °C

3: LDA / tetrahydrofuran / -78 - 20 °C

4: 77 percent / TiCl₄ / CH₂Cl₂ / 1 h / -23 °C

5: 1.) sodium metaperiodate / 1.) MeOH-H₂O (9:1), 20 deg C, 16 h; 2.) CCl₄, 60 deg C, 4 h

With sodium periodate; titanium tetrachloride; lithium diisopropyl amide; W-2 Raney nickel; In tetrahydrofuran; ethanol; dichloromethane; acetone;
DOI:10.1016/S0040-4020(01)86667-9

Reference yield:

: 71268-63-8
2-methyl-2-(phenylthiomethyl)-1-cyclohexanone

: 71268-58-1
2,2-dimethyl-6-methylenecyclohexan-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / W-2 Raney nickel / acetone; ethanol / 2 h / 20 °C

2: LDA / tetrahydrofuran / -78 - 20 °C

3: 77 percent / TiCl₄ / CH₂Cl₂ / 1 h / -23 °C

4: 1.) sodium metaperiodate / 1.) MeOH-H₂O (9:1), 20 deg C, 16 h; 2.) CCl₄, 60 deg C, 4 h

With sodium periodate; titanium tetrachloride; lithium diisopropyl amide; W-2 Raney nickel; In tetrahydrofuran; ethanol; dichloromethane; acetone;
DOI:10.1016/S0040-4020(01)86667-9