2-Buten-1-ol, acetate, (2Z)-

Base Information

• Chemical Name: 2-Buten-1-ol, acetate, (2Z)-
• CAS No.: 7204-36-6
• Molecular Formula: C6H10O2
• Molecular Weight: 114.144
• Mol file: 7204-36-6.mol

Synonyms:

Chemical Property of 2-Buten-1-ol, acetate, (2Z)-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Buten-1-ol, acetate, (2Z)-

There total 3 articles about 2-Buten-1-ol, acetate, (2Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-acetoxy-3-butene (1576-84-7) → (Z)-2-butene-1-yl acetate (7204-36-6) + trans-2-butenyl acetate (7204-29-7)

Guidance literature:

With 2,6-di-tert-butyl-pyridine; C₂₆H₄₆IrNO₇P⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; In 1,2-dichloro-ethane; at 50 ℃; for 24h; Time; regioselective reaction; Inert atmosphere;

DOI:10.1021/jacs.0c11601

Reference yield:

(Z)-2-Butene (590-18-1) + tert-butyl peroxyacetate (107-71-1) → (Z)-2-butene-1-yl acetate (7204-36-6) + trans-2-butenyl acetate (7204-29-7) + 2-acetoxy-3-butene (6737-11-7)

Guidance literature:

With copper diacetate; In benzene; at 70 ℃; for 120h; Product distribution; further reagents, solvents, reaction time;

DOI:10.1021/ja00286a020

Reference yield:

2-acetoxy-3-butene (6737-11-7) → (Z)-2-butene-1-yl acetate (7204-36-6) + methyl (E)-pent-3-enoate (818-58-6)

Guidance literature:

With perchloric acid; In acetic acid; at 25 - 50 ℃; Equilibrium constant; Kinetics; Thermodynamic data; other temperature;

DOI:10.1021/ja00748a020

upstream raw materials:

2-acetoxy-3-butene

(Z)-2-Butene

tert-butyl peroxyacetate

1-acetoxy-3-butene

Downstream raw materials:

5-methyl-5-nitrohexan-2-one

(E)-5-Methyl-5-nitro-hex-2-ene

2-butenyl p-tolyl sulfone

(R)-1-(but-3-en-2-ylsulfonyl)-4-methylbenzene

Refernces