ACETIC ACID 3-BUTEN-2-YL ESTER

Base Information

• Chemical Name: ACETIC ACID 3-BUTEN-2-YL ESTER
• CAS No.: 6737-11-7
• Molecular Formula: C6H10 O2
• Molecular Weight: 114.144
• Hs Code.: 2916199590
• Mol file: 6737-11-7.mol

Synonyms:3-Buten-2-ol,acetate (6CI,7CI,8CI,9CI); 1-Buten-3-yl acetate; 1-Methyl-2-propenyl acetate;1-Methylallyl acetate; 3-Acetoxy-1-butene; 3-Buten-2-yl acetate; 3-Butene-2-ylacetate; Methylvinylcarbinol acetate; a-Methylallyl acetate

Chemical Property of ACETIC ACID 3-BUTEN-2-YL ESTER

Chemical Property:

• Refractive Index: 1.4020-1.4050
• Boiling Point: 112 °C
• Flash Point: 29.4oC
• PSA: 26.30000
• Density: 0.90
• LogP: 1.12400
• Storage Temp.: 2-8°C
• Water Solubility.: 13.03g/L(26 oC)

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-Buten-2-yl Acetate >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ACETIC ACID 3-BUTEN-2-YL ESTER

There total 11 articles about ACETIC ACID 3-BUTEN-2-YL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic acid (64-19-7,77671-22-8) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → 2-acetoxy-3-butene (6737-11-7) + crotyl acetate (628-08-0) + 4-ethenylcyclohexene (100-40-3)

Guidance literature:

Amberlyst 15H (unwashed); at 60 ℃; for 24h; Product distribution / selectivity;

Reference yield:

acetic acid (64-19-7,77671-22-8) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → trans-2-butenyl acetate (7204-29-7) + octa-1,3,7-triene (1002-35-3) + 2-acetoxy-3-butene (6737-11-7) + octa-1,7-dien-3-yl acetate (3491-26-7) + 1-acetoxy-3,7-octadiene

Guidance literature:

With sodium 3-(bis(3,5-bis(trifluoromethyl)phenyl)phosphaneyl)benzenesulfonate; 3-(2-methoxyethyl)-1-methylimidazolium acetate; palladium diacetate; at 70 ℃; for 5h; Reagent/catalyst; Temperature; Catalytic behavior; Inert atmosphere;

DOI:10.1002/cctc.201402943

Reference yield:

1,3-diacetoxybutane (1117-31-3) → 2,3-dimethylbutene (590-19-2) + 2-acetoxy-3-butene (6737-11-7)

Guidance literature:

at 472 ℃;

upstream raw materials:

tert-Butyl peroxybenzoate

trans-2-Butene

1-butylene

tert-butyl peroxyacetate

Downstream raw materials:

acetic acid-(3-cyclohexyl-1-methyl-propyl ester)

(Z)-2-butene-1-yl acetate

methyl (E)-pent-3-enoate

(Z)-but-2-enyl(phenyl)selane