Bis(4-bromophenyl)-methylarsane

Base Information

• Chemical Name: Bis(4-bromophenyl)-methylarsane
• CAS No.: 6309-86-0
• Molecular Formula: C₁₃H₁₁AsBr₂
• Molecular Weight: 401.96
• Hs Code.: 2931900090
• NSC Number: 41642
• DSSTox Substance ID: DTXSID00285390
• Wikidata: Q82020745
• Mol file: 6309-86-0.mol

Synonyms:6309-86-0;bis(4-bromophenyl)-methylarsane;NSC41642;ANTINEOPLASTIC-41642;DTXSID00285390;NSC-41642

Chemical Property of Bis(4-bromophenyl)-methylarsane

Chemical Property:

• Vapor Pressure: 2.94E-05mmHg at 25°C
• Boiling Point: 367.2°C at 760 mmHg
• Flash Point: 205.4°C
• PSA: 0.00000
• LogP: 3.45040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 401.84230
• Heavy Atom Count: 16
• Complexity: 184

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[As](C1=CC=C(C=C1)Br)C2=CC=C(C=C2)Br

Technology Process of Bis(4-bromophenyl)-methylarsane

There total 1 articles about Bis(4-bromophenyl)-methylarsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-bromo-phenyl)-iodo-methyl-arsine (861788-42-3) + (4-bromophenyl)magnesium bromide (18620-02-5) → bis-(4-bromo-phenyl)-methyl-arsine (6309-86-0)

Guidance literature:

With diethyl ether;

DOI:10.1021/ja01847a061

Reference yield:

bis-(4-bromo-phenyl)-methyl-arsine (6309-86-0) → bis-(4-bromo-phenyl)-methyl-arsine oxide (857587-59-8)

Guidance literature:

With potassium permanganate; acetone;

DOI:10.1021/ja01847a061

Reference yield:

bis-(4-bromo-phenyl)-methyl-arsine (6309-86-0) → bis-(4-bromo-3-nitro-phenyl)-methyl-arsine (5449-91-2)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium permanganate; acetone

2: sulfuric acid; nitric acid

3: hypophosphoric acid; hydrogen iodide; aqueous acetic acid

With potassium permanganate; sulfuric acid; hydrogen iodide; nitric acid; hypophosphoric acid; acetic acid; acetone;

DOI:10.1021/ja01847a061

upstream raw materials:

(4-bromo-phenyl)-iodo-methyl-arsine

(4-bromophenyl)magnesium bromide

Downstream raw materials:

bis-(4-bromo-phenyl)-methyl-arsine oxide

bis-(4-bromo-3-nitro-phenyl)-methyl-arsine

bis-(4-hydroxy-3-nitro-phenyl)-methyl-arsine oxide

bis-(4-bromo-3-nitro-phenyl)-methyl-arsine oxide