bis(4-bromo-3-nitrophenyl)(methyl)arsane

Base Information

• Chemical Name: bis(4-bromo-3-nitrophenyl)(methyl)arsane
• CAS No.: 5449-91-2
• Molecular Formula: C₁₃H₉AsBr₂N₂O₄
• Molecular Weight: 491.955
• Mol file: 5449-91-2.mol

Synonyms:

Chemical Property of bis(4-bromo-3-nitrophenyl)(methyl)arsane

Chemical Property:

• Vapor Pressure: 1.28E-07mmHg at 25°C
• Boiling Point: 442.7°Cat760mmHg
• Flash Point: 221.6°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-bromo-3-nitrophenyl)(methyl)arsane

There total 5 articles about bis(4-bromo-3-nitrophenyl)(methyl)arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis-(4-bromo-3-nitro-phenyl)-methyl-arsine oxide (857587-61-2) → bis-(4-bromo-3-nitro-phenyl)-methyl-arsine (5449-91-2)

Guidance literature:

With hydrogen iodide; hypophosphoric acid; acetic acid;

DOI:10.1021/ja01847a061

Reference yield:

(4-bromo-phenyl)-iodo-methyl-arsine (861788-42-3) → bis-(4-bromo-3-nitro-phenyl)-methyl-arsine (5449-91-2)

Guidance literature:

Multi-step reaction with 4 steps

1: diethyl ether

2: potassium permanganate; acetone

3: sulfuric acid; nitric acid

4: hypophosphoric acid; hydrogen iodide; aqueous acetic acid

With potassium permanganate; diethyl ether; sulfuric acid; hydrogen iodide; nitric acid; hypophosphoric acid; acetic acid; acetone;

DOI:10.1021/ja01847a061

Reference yield:

bis-(4-bromo-phenyl)-methyl-arsine (6309-86-0) → bis-(4-bromo-3-nitro-phenyl)-methyl-arsine (5449-91-2)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium permanganate; acetone

2: sulfuric acid; nitric acid

3: hypophosphoric acid; hydrogen iodide; aqueous acetic acid

With potassium permanganate; sulfuric acid; hydrogen iodide; nitric acid; hypophosphoric acid; acetic acid; acetone;

DOI:10.1021/ja01847a061

upstream raw materials:

bis-(4-bromo-3-nitro-phenyl)-methyl-arsine oxide

(4-bromo-phenyl)-iodo-methyl-arsine

bis-(4-bromo-phenyl)-methyl-arsine oxide

bis-(4-bromo-phenyl)-methyl-arsine